Sökning: "micellar solution"

Visar resultat 1 - 5 av 24 avhandlingar innehållade orden micellar solution.

1. 1. Nuclear Magnetic Relaxation in Micellar Solution and Lyotropic Liquid Crystals. Tools and Applications

   Författare :Ruslan Sitnikov; KTH; []
   Nyckelord :NMR; NMR relaxation dispersion; NMR spectrometer; low NMR frequencies; NMR duplexer; NMR preamplifier; NMR lock; surfactant systems; micellar solutions; lyotropic liquid crystals; cubic mesophase;

   Sammanfattning : Structurally, this Thesis is divided into two parts thatdescribe (i) the hardware development for NMR relaxationstudies and (ii) its applications for studies of the surfactantsystems.The developed hardware solutions allow to expand thefrequency range covered by conventional NMR spectrometers tomake NMR experiments feasible at resonance frequencies down to100 kHz. LÄS MER

3. 2. NMR Studies of Colloidal Systems in and out of Equilibrium

   Författare :Pavel V. Yushmanov; Peter Stilbs; Terence Gosgrove; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; stopped-flow NMR; temperature-jump NMR; crossrelaxation; NMR; NMR probe; fluorosurfactant; micellar kinetics; micellar structure; Physical chemistry; Fysikalisk kemi;

   Sammanfattning : The Thesis describes (i) the development of add-on instrumentation extending the capabilities of conventional NMR spectrometers and (ii) the application of the designed equipments and techniques for investigating various colloidal systems. The new equipments are: Novel designs of stopped-flow and temperature–jump inserts intended for conventional Bruker wide-bore superconductive magnets. LÄS MER

4. 3. Enzyme Immunoassay in Combination with Liquid Chromatography for Sensitive and Selective Determination of Drugs in Biosamples

   Författare :Ulf Lövgren; Centrum för analys och syntes; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Analytical chemistry; amplification; alkaline phosphatase; enzyme immunoassay; liquid chromatography; flow-injection; micellar; Analytisk kemi;

   Sammanfattning : Two different sensitive microtitre-plate based enzyme immunoassays were developed and evaluated for determination of the model drug compound, budesonide, in blood plasma. In the first approach, high sensitivity was obtained by using amperometric detection in a flow injection system for determination of the enzyme product p-aminophenol. LÄS MER

5. 4. Ternary Block Copolymer Systems - Phase Behaviour and Phase Structure

   Författare :Birgitta Svensson; Fysikalisk kemi; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Theoretical chemistry; lyotropic; thermotropic; SANS; SAXS; scattering; semicrystalline; reverse micelle; micellar solution; liquid crystalline; phase diagram; phase behaviour; block copolymer; pluronic; poly ethylene oxide ; poly propylene oxide ; quantum chemistry; Teoretisk kemi; kvantkemi;

   Sammanfattning : Ternary isothermal (25°C) polyoxyalkylene triblock block copolymer ((EO)x(PO)y(EO)x where x is the number of ethylene oxide, EO, segments and y is the number of propylene oxide, PO, segments) systems with water and p-xylene as selective solvents for the PEO and PPO blocks, respectively, were chosen as study systems in this thesis as these ternary systems are good model systems for the self-assembly of block copolymers. The phase behaviour has been studied at varied block copolymer molecular weight and relative PEO/PPO block ratio. LÄS MER

7. 5. Scattering Studies of Macromolecules in Solution

   Författare :David Löf; Fysikalisk kemi; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Bacteriophage lambda; Dynamic Light Scattering; Time-Resolved; Mixed Micelles; Nonionic Surfactant; Triblock Copolymer; Calorimetry; SLS; Rheology; DLS; SAXS;

   Sammanfattning : The sphere-to-rod transition of nonionic micelles of the PEO-PPO-PEO triblock copolymer P123 and the surfactant C12EO6 was studied using dynamic and static light scattering, small angel X-ray scattering, rheology and calorimetry. The transition temperature was dependent of the C12EO6/P123 molar ratio, which means that a larger content of C12EO6 yields a higher transition temperature. LÄS MER