Sökning: "metastable zone"

Visar resultat 1 - 5 av 6 avhandlingar innehållade orden metastable zone.

  1. 1. Structural, Kinetic and Thermodynamic Aspects of the Crystal Polymorphism of Substituted Monocyclic Aromatic Compounds

    Författare :Michael Svärd; Åke Rasmuson; Hugo Meekes; KTH; []
    Nyckelord :ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; Polymorphism; crystallization; thermodynamics; kinetics; nucleation; crystallography; solubility; phase equilibria; polymorphic transformation; solution history; metastable zone; classical theory of nucleation; two-step theory of nucleation; cluster; crystal structure prediction; lattice energy; molecular mechanics; force field; electrostatic potential; potential energy hypersurface; m-aminobenzoic acid; m-hydroxybenzoic acid; Chemical engineering; Kemiteknik;

    Sammanfattning : This work concerns the interrelationship between thermodynamic, kinetic and structural aspects of crystal polymorphism. It is both experimental and theoretical, and limited with respect to compounds to substituted monocyclic aromatics. LÄS MER

  2. 2. Solid-liquid Phase Equilibria and Crystallization of Disubstituted Benzene Derivatives

    Författare :Fredrik Nordström; Åke Rasmuson; Gerard Coquerel; KTH; []
    Nyckelord :ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; Salicylic acid; m-hydroxybenzoic acid; p-hydroxybenzoic acid; salicylamide; m-aminobenzoic acid; p-aminobenzoic acid; solubility; solid-liquid equilibria; thermodynamics; activity of the solid phase; ideal solubility; activity coefficient; van t Hoff enthalpy of solution; solid state; solution properties; metastable zone width; primary nucleation; nucleation kinetics; Chemical engineering; Kemiteknik;

    Sammanfattning : The Ph.D. project compiled in this thesis has focused on the role of the solvent in solid-liquid phase equilibria and in nucleation kinetics. Six organic substances have been selected as model compounds, viz. LÄS MER

  3. 3. Characterization of oxide scales formed on FeCrAl alloys at high temperatures

    Författare :Josefin Engkvist; []
    Nyckelord :ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY;

    Sammanfattning : This thesis focuses on the characterization of oxide scales formed on FeCrAl alloys at high temperatures. The effect of water vapour on commercial FeCrAl alloys oxidized in both dry and humid O2 has been investigated. LÄS MER

  4. 4. Electronic Structure of Transition Metal Complexes in Silicon

    Författare :Per Tidlund; Fasta tillståndets fysik; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; uniaxial stress; FTIR; Zeeman spectroscopy; deep levels; phonon-assisted Fano resonances; Physics; Fysik; Au; Fysicumarkivet A:1998:Tidlund; PtLi; AuLi; Pt; Transition Metals; Silicon;

    Sammanfattning : This thesis consists of experimental studies of the electronic of electronic structure of the transition metals Au and Pt, and the transition metal complexes, FeIn, PtLi, and AuLi in silicon. Fourier transform infrared spectroscopy, photoconductivity, uniaxial stress- and Zeeman spectroscopy are employed. LÄS MER

  5. 5. Influence of Admixtures on Crystal Nucleation of Vanillin

    Författare :Osvaldo Pino-García; KTH; []
    Nyckelord :Crystallization; nucleation; vanillin; admixtures; additives; impurities; induction time; interfacial energy; molecular modelling; interaction energy;

    Sammanfattning : Admixtures like reactants and byproducts are solublenon-crystallizing compounds that can be present in industrialsolutions and affect crystallization of the main substance.This thesis provides experimental and molecular modellingresults on the influence of admixtures on crystal nucleation ofvanillin (VAN). LÄS MER