Sökning: "metal-metal bond"

Hittade 5 avhandlingar innehållade orden metal-metal bond.

  1. 1. Compounds with Non-Buttressed Metal-Metal Bond between Platinum and Thallium. Model Systems for Photoinduced Two-Electron-Transfer

    Författare :Mikhail Maliarik; KTH; []
    Nyckelord :thallium; platinum; cyanide; metal-metal bond; non-buttressed; heterometallic; photoinduced; electron transfer; redox reaction; NMR; chemical shift; spin-spin coupling constant; Raman; EXAFS; X-ray diffraction; equilibrium; oxidation state; oxidative;

    Sammanfattning : A new family of oligonuclear cyano compounds incorporatingtransition (Pt) and main group (Tl) metals bound with anon-buttressed Pt-Tl bond was synthesised in aqueous solution.The metal-metal linkage is formed in the reaction betweenplatinum and thallium in their stable oxidation forms, Pt(II)and Tl(III), orvice versa: Pt(IV) and Tl(I). LÄS MER

  3. 2. Metal-metal bond between transition and main-group metals : heterobimetallic platinum-thallium cyanide compounds

    Författare :Mikhail Maliarik; KTH; []
    Nyckelord :;

    Sammanfattning : .... LÄS MER

  4. 3. On Thallium (III) and binuclear platinum-thallium complexes with N-donor ligands in solution and in solid

    Författare :Guibin Ma; KTH; []
    Nyckelord :thallium; platinum; cyanide; n-donor ligand; metal-metal bond multinuclear NMR; raman spectroscopy;

    Sammanfattning : This thesis describes the synthesis, structure, equilibriaand other properties of novel thallium(III) monomeric andplatinum-bonded complexes with nitrogen donor ligandsethylenediamine, diethylenetriamine, triethylenetetramine,porphyrin, 2,2'-bipyridine and 1,10-phenanthroline in solutionand in solid.The existence of three complexes withthe general formula[Tl(en)n]3+(n = 1-3) and their overall stability constantshave been established in pyridine. LÄS MER

  5. 4. Formation and Decomposition of Platinum–Thallium Bond, Kinetics and Mechanism. Structural Characterization of Some Metal Cyanides in the Solid State

    Författare :Péter Nagy; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; metal–metal bond; platinum; thallium; kinetics; mechanism; stopped flow; oxidative addition; cyano complexes; edta; redox reaction; metal cyanides; X–ray diffraction; Raman; NMR; mercury; palladium; nickel; one dimensional wire;

    Sammanfattning : The kinetic and mechanistic features of a new series ofplatinum-thallium cyano compounds containing a direct andunsupported by ligands metal-metal bond have been studied insolution, using standard mix–and–measurespectrophotometric technique and stopped–flow method.These reactions are interpreted as oxidative addition of the cspecies to the square planar Pt(CN)42-complex. LÄS MER

  7. 5. On the role of Alkaline Earth Metal Oxides in Environmental Catalysis

    Författare :Peter Broqvist; Chalmers tekniska högskola; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY;

    Sammanfattning : In heterogeneous catalysis, metal oxides have various roles: as catalysts, as support material for catalytically active metal particles, as promoters, as stabilizers, or as storage materials. Although their main application is as support material, their role as promoter or storage material becomes increasingly important as emission legislations are becoming more stringent. LÄS MER