Sökning: "metal stretching"

Visar resultat 1 - 5 av 13 avhandlingar innehållade orden metal stretching.

  1. 1. Compounds with Non-Buttressed Metal-Metal Bond between Platinum and Thallium. Model Systems for Photoinduced Two-Electron-Transfer

    Författare :Mikhail Maliarik; KTH; []
    Nyckelord :thallium; platinum; cyanide; metal-metal bond; non-buttressed; heterometallic; photoinduced; electron transfer; redox reaction; NMR; chemical shift; spin-spin coupling constant; Raman; EXAFS; X-ray diffraction; equilibrium; oxidation state; oxidative;

    Sammanfattning : A new family of oligonuclear cyano compounds incorporatingtransition (Pt) and main group (Tl) metals bound with anon-buttressed Pt-Tl bond was synthesised in aqueous solution.The metal-metal linkage is formed in the reaction betweenplatinum and thallium in their stable oxidation forms, Pt(II)and Tl(III), orvice versa: Pt(IV) and Tl(I). LÄS MER

  3. 2. Numerical and computer techniques in finite element analysis

    Författare :Hans Wennerström; Chalmers tekniska högskola; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Finite element; Poisson s equation; Navier s equations; metal stretching; Navier-Stokes equations; numerical integration; computer program;

    Sammanfattning : .... LÄS MER

  4. 3. Structural and Spectroscopic Studies of Solvated Metal Ions

    Författare :Alireza Abbasi; Magnus Sandström; Ernö Brucher; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Coordination; Solvation; X-ray diffraction; EXAFS; IR; Raman; Normal coordinate analysis; trivalent metal ions; dmso; triflate; hydration; Chemistry; Kemi;

    Sammanfattning : Crystallographic and spectroscopic studies have been performed of structures, coordination and chemical bonding for series of trivalent metal ions solvated by two oxygen-coordinating solvents, water and dimethyl sulfoxide (DMSO). The hydrated scandium(III) and lanthanoid(III) ions, La to Lu, are surrounded by tricapped trigonal prisms of aqua ligands in the isomorphous series of trifluoromethanesulfonates, [M(H2O)n](CF3SO3)3. LÄS MER

  5. 4. Classical and Car-Parrinello Molecular Dynamics Simulations of Polyvalent Metal Ions in Water

    Författare :Sami Amira; Kersti Hermansson; Imre Bako; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Inorganic chemistry; Car-Parrinello molecular dynamics simulations; ab initio calculations; ion; copper; aluminium; metal ion; water; aqueous solution; solvation; Oorganisk kemi; Inorganic chemistry; Oorganisk kemi;

    Sammanfattning : The aqueous solvation of metal ions is one of the long-standing and complex problems in chemistry, with implications for and applications in a broad range of biochemical and electrochemical systems, where water is the all-pervasive medium.This thesis describes computer simulations of Al3+(aq), Fe2+(aq), Fe3+(aq) and Cu2+(aq). LÄS MER

  7. 5. Mathematical Analysis of Forced Convective Flow Due to Stretching Sheet and Instabilities of Natural Convective Flow

    Författare :Prashant G Metri; Sergei Silvestrov; Rebei Bel-Fdhila; Mälardalens högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Boundary layer theory; Heat and Mass transfer; Partial differential equations; Stretching sheet; Mathematics Applied Mathematics; matematik tillämpad matematik;

    Sammanfattning : The investigations presented in the thesis are theoretical studies of magnetohydrodynamic flows, heat and mass transfer in Newtonian/non-Newtonian cooling liquids, due to horizontal/vertical stretching sheet. The theoretical studies include the effect of magnetic field, uniform and non-uniform heat source/sink (flow and temperature dependent heat source/sink) effects. LÄS MER