Sökning: "martin lawoko"

Visar resultat 1 - 5 av 8 avhandlingar innehållade orden martin lawoko.

  1. 1. Lignin polysaccharide networks in softwood and chemical pulps : characterisation, structure and reactivity

    Författare :Martin Lawoko; Göran Gellerstedt; Gösta Brunow; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Cellulose and paper engineering; Cellulosa- och pappersteknik;

    Sammanfattning : The chemical interactions between the main wood components i.e., cellulose, hemicelluloses and lignin are of fundamental importance for understanding the chemical aspects of wood formation and its reactivity during fibre processing e.g during chemical pulping of wood. LÄS MER

  3. 2. Wood Hemicelluloses - Fundamental Insights on Biological and Technical Properties

    Författare :Jennie Berglund; Mikael Lindström; Gunnar Henriksson; Francisco Vilaplana; Jakob Wohlert; Martin Lawoko; Maija Tenkanen; KTH; []
    Nyckelord :LANTBRUKSVETENSKAPER; AGRICULTURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; LANTBRUKSVETENSKAPER; AGRICULTURAL SCIENCES; hemicellulose; wood; glucomannan; xylan; structure; acetylation; flexibility; solubility; interaction with cellulose; stability.; hemicellulosa; trä; glukomannan; xylan; struktur; acetylering; flexibilitet; löslighet; interaktion med cellulosa; stabilitet.; Fiber- och polymervetenskap; Fibre and Polymer Science;

    Sammanfattning : Hemicelluloses are a group of heterogeneous polysaccharides representing around 30 % of wood where the dominating types are xylans, glucomannans and xyloglucans. Hemicelluloses complex molecular structure makes it difficult to understand the relationship between structure and properties entirely, and their biological role is not yet fully verified. LÄS MER

  4. 3. Fundamental Aspects of Lignin Carbohydrate Complexes (LCC) : Mechanisms, Recalcitrance and Material concepts

    Författare :Nicola Giummarella; Martin Lawoko; Gunnar Henriksson; Arthur J. Ragauskas; KTH; []
    Nyckelord :LANTBRUKSVETENSKAPER; AGRICULTURAL SCIENCES; Lignin Carbohydrates Complexes; Phenyl Glycosides; Benzyl Ethers; Benzyl and γ-esters; Universal Mild Quantitative fractionation; LCC mechanism formation; Extracellular lignin; Dehydogenation polymer; Autohydrolysis; Recalcitrance; Acetylation role; HSQC; HMBC; HSQC-TOCSY; 13C; 31P NMR; Thioacidolysis-GC; SEC; Green; Biomimetic; One-pot-lignin functionalization; Lignin platform material.; Fiber- och polymervetenskap; Fibre and Polymer Science;

    Sammanfattning : Covalent bonds between lignin and carbohydrates, forming a matrix referred to as lignin carbohydrate complexes (LCC), remain one of the most controversial topics in wood chemistry. A key issue is whether they are formed during chemical and mechanical pretreatments of the compact wood structure or actually present in wood prior to isolation. LÄS MER

  5. 4. Protected Lignin Biorefining: Fundamental Insights on Lignin Reactivity

    Författare :Maria Karlsson; Martin Lawoko; Åsa Emmer; Olena Sevastyanova; John Ralph; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Sustainability; lignin; biorefinery; cyclic organosolv extraction; preserved structure; NMR; MALDI-TOF MS; Hållbarhet; lignin; bioraffinaderi; cyklisk organosolv extraktion; bevarad struktur; NMR; MALDI-TOF MS; Fiber- och polymervetenskap; Fibre and Polymer Science;

    Sammanfattning : The potential to utilize lignin, which constitutes as much as 15-30% of the biomass, needs further evaluation. In the transition towards a bioeconomy, lignin has the potential to replace fossil-based phenols. Attempts to valorize the available technical lignins are ongoing; however, that lignin suffers from molecular heterogeneity. LÄS MER

  7. 5. Lignin-Based Thermosets with Tunable Mechanical and Morphological Properties : A Study of Structure-Property Relationships

    Författare :Iuliana Ribca; Mats Johansson; Martin Lawoko; Stephan V. Roth; Mika Sipponen; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; NATURVETENSKAP; NATURAL SCIENCES; Softwood; hardwood; technical lignin; solvent fractionation; allylation; thiol-ene thermosets; thioether linkage; wide-angle X-ray scattering; π-π stacking interactions; Barrträ; lövträ; tekniskt lignin; lösningsmedelsfraktionering; allylering; tiol-en-härdplaster; tioeterbindning; vidvinkelröntgenspridning; π-π staplingsinteraktioner; Fiber- och polymervetenskap; Fibre and Polymer Science;

    Sammanfattning : Nowadays, there is an urgent need to decrease our dependence on fossilresources and shift towards the use of renewable resources for advancingsustainable development. Utilizing renewable and bio-based raw materials,such as lignocellulosic biomass, for designing new materials is a promisingapproach to promote this objective. LÄS MER