Sökning: "manganese systems"

Visar resultat 16 - 20 av 53 avhandlingar innehållade orden manganese systems.

1. 16. An Investigation of Peroxidase Activity in Biomimetic and Biological Systems

   Författare :Ekaterina Ryabova; Kemiska institutionen; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; metabolism; Metabolism; enzymologi; Proteiner; enzymology; Proteins; hemoglobin; catalysis; peptide; peroxidase; protoporphyrin IX; Biokemi; Biochemistry;

   Sammanfattning : In order to create a heme environment which permits biomimicry of heme-containing plant peroxidases and investigate the role played by the vinyl side chains of the porphyrin ring on the stability and, possibly, catalytic activity of model compounds, a number of new synthetic microperoxidases -– hemin-6(7)-gly-his methyl ester (HGH) and hemin-6(7)-gly-gly-his methyl ester (HGGH) and hemin-6,7-bis(gly-gly-his methyl ester) (H2GGH) as well as mesohemin-6(7)-gly-gly-his methyl ester (MGGH) and deuterohemin-6(7)-gly-gly-his methyl ester (DGGH) have been prepared by condensation of a peptide residue with the propionic side chains of hemin, mesohemin and deuterohemin, respectively. Reactivity studies towards different organic and inorganic substrates showed that not only five- but also six-coordinate hemin peptide complexes catalyze the oxidation of substrates by H2O2. LÄS MER

3. 17. Crystallographic Studies of Ternary Chalcogenides and Organic Semiconductors

   Författare :Céline Besnard; Centrum för analys och syntes; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; phase equilibria; Kondenserade materiens egenskaper:struktur; egenskaper termiska och mekaniska ; kristallografi; fasjämvikt; crystallography; thermal and mechanical properties; Condensed matter:stucture; thiazine derivatives; quinoline derivatives; hexacene-quinone; substituted tetracene; rubrene derivatives; manganese telluride; organic semiconductors; niobium sulfide intercalation compounds; thiospinel;

   Sammanfattning : X-ray diffraction methods have been used to study the crystal structure of different compounds, both organic and inorganic. The inorganic compounds were all synthesized by solid state reactions. A new compound, Re4As6S3, was synthesized and its structure was solved by Rietveld methods. LÄS MER

4. 18. Chromatography and extraction techniques for new evaluation methods of polyolefins long-term performance

   Författare :Lina Burman; Ann-Christine Albertsson; Marek Kowalczuk; KTH; []
   Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Chemical engineering; polymer; chromatographic fingerprinting; gas-chromatography – mass spectrometry; GC-MS; degradable polyethylene; prooxidant systems; chemiluminescence; oxidation; degradation mechanisms; accelerated ageing; antioxidants; transformation products; microwave assisted extraction; MAE; solid-phase microextraction; SPME; volatiles; solid phase extraction; SPE; Kemiteknik; Chemical engineering; Kemiteknik;

   Sammanfattning : Chromatography and extraction techniques, and also chemiluminescence have been utilized to develop new rapid and informative tools in the evaluation of long-term properties and environmental effects of polymeric materials. Methods were developed for classification of materials and for early and rapid degradation detection. LÄS MER

5. 19. Use of Bed Materials in Dual Fluidized Bed (DFB) Systems

   Författare :Jelena Maric; Chalmers tekniska högskola; []
   Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Bed material; Chemical looping reforming; Dual Fluidized Bed;

   Sammanfattning : Dual Fluidized Bed (DFB) gasification is one alternative for the production of biofuels. In a DFB gasification process, the bed material plays a crucial role. Primary role of the bed material is to provide the heat needed for the gasification reaction. LÄS MER

7. 20. Sustainable Arsenic Mitigation A Strategy for Scaling-up Safe Water Access : A Strategy for Scaling-up Safe Water Access

   Författare :Mohammed Hossain; Prosun Bhattacharya; Marinus Eric Donselaar; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; Bangladesh; drinking water; arsenic mitigation; local tubewell driller; sediment color tool; low-manganese; Intermediate Deep aquifer; Land and Water Resources Engineering; Mark- och vattenteknik;

   Sammanfattning : In rural Bangladesh, the drinking water supply is mostly dependent upon manually operated hand pumped tubewells, installed by the local community. The presence of natural arsenic (As) in groundwater and its wide scale occurrence has drastically reduced the safe water access across the country and put tens of millions of people under health risk. LÄS MER