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1. Synthesis of low molecular weight carbohydrates
Sammanfattning : .... LÄS MER
2. Synthesis and transformation of some low molecular weight carbohydrates
Sammanfattning : A one-step transformation of hydroxyl groups in carbohydrates to bromo groups is presented.The usefulness of ρ-methoxybenzyl as a protecting group of the anomeric center is examined. Reductive elimination by treatment of acetylated deoxyhalo sugar derivatives using zinc powder in ethanol containing acetic acid to give unsaturation is described. LÄS MER
3. Structural studies of two bacterial polysaccharide antigens : synthesis and chemical modification of low molecular weight carbohydrates
Sammanfattning : The structures of two bacterial antigens, one a capsular polysaccharide from Klebsiella K66 and the other a lipopolysaccharide from Escherichia coli 0:6, have been determined, using specific degradations and spectrochemical studies. Two glycosidation methods are described. LÄS MER
4. Effects of Processing on Dietary Fibre in Vegetables
Sammanfattning : Several beneficial effects have been connected with dietary fibre. Insoluble fibre has a good faecal bulking capacity, whereas soluble and viscous dietary fibre has been shown to have beneficial effects on carbohydrate and lipid metabolism. LÄS MER
5. Stereo and regio controlled halogenation, and synthesis of low molecular weight carbohydrates
Sammanfattning : The regio- and stereoselective introduction of halogens as well as unsaturation into carbohydrates is investigated with triphenylphosphine - halide systems. Three different glycosidation methods are presented. LÄS MER