Sökning: "lignin model"

Visar resultat 1 - 5 av 99 avhandlingar innehållade orden lignin model.

  1. 1. Palladium-catalyzed lignin valorization : Towards a lignin-based biorefinery

    Författare :Maxim Galkin; Joseph Samec; Rafael Luque; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; LANTBRUKSVETENSKAPER; AGRICULTURAL SCIENCES; Lignin; Heterogeneous Catalysis; Palladium; Biomass; Depolymerization; Reduction; Oxidation; Biorefinery; Transfer Hydrogenolysis; Organic Chemistry; Organisk kemi;

    Sammanfattning : The work described in this thesis focuses on the cleavage of the β-O-4′ bond, which is the most abundant interunit linkage in the lignin polymer.In the first part, three methods based on palladium catalysis have been developed and their applicability has been verified using lignin model compounds. LÄS MER

  3. 2. Biosynthesis, interactions, and structure of native lignin

    Författare :Ioanna Sapouna; Lauren S. McKee; Francisco Vilaplana; Claudia Crestini; KTH; []
    Nyckelord :LANTBRUKSVETENSKAPER; AGRICULTURAL SCIENCES; lignin; biomass valorization; extraction; tissue culture; lignin nanoparticles; wood aerogels; lignin; biomassavalorisering; extraktion; vävnadsodling; lignin nanopartiklar; trä aerogeler; Fiber- och polymervetenskap; Fibre and Polymer Science;

    Sammanfattning : Wood biomass is an important resource in the development ofstrategies towards replacement of fossil-based materials. Woodcomprises cellulose, hemicelluloses and lignin, in amounts thatvary between species. LÄS MER

  4. 3. Lignin-carbohydrate complexes: Model compounds synthesis

    Författare :Filip Nylander; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; Lignin-carbohydrate complex; lignin model compounds; lignocellulose;

    Sammanfattning : In lignocellulose there is a recalcitrant interaction by covalent and non-covalent bonds called the lignin-carbohydrate complex. This interaction has been the subject of studies trying to unveil its chemical structure, to understand the mechanims involved in its formation and to determine its influence on practical applications such as the process of turning biomass into ethanol. LÄS MER

  5. 4. Partitioning of Drugs and Lignin Precursor Models into Artificial Membranes

    Författare :Elisabet Boija; Gunnar Johansson; Per Lundahl; Christine Lagerquist Hägglund; Marja-Liisa Riekkola; Uppsala universitet; []
    Nyckelord :Biochemistry; Bilayer disk; Capillary electrophoresis; Detergent; Drug; Electrostatic interaction; Hydrophobic interaction; Immobilized liposome chromatography; Lignin; Lignin precursor model; Liposome; Membrane model; Octanol water partitioning; Partitioning; Phospholipid; Phospholipid bilayer; Sterol; Biokemi;

    Sammanfattning : The main aim of this thesis was to characterize membrane-solute interactions using artificial membranes in immobilized liposome chromatography or capillary electrophoresis. The partitioning of a solute into a cell membrane is an essential step in diffusion across the membrane. LÄS MER

  7. 5. Lignin Model Compounds: Synthesis, Stereochemistry and Acidolysis

    Författare :Shiming Li; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; boric acid complexes; Arylglycerol b-aryl ethers; stereochemistry; 3-Diaryl-2-propen-1-ols; 1; Phenylcoumarans; lignin model compounds; acidolysis; ion-exchange chromatography; 3-propanediols; 2-Diaryl-1; 2; X-ray crystallography;

    Sammanfattning : Lignin model compounds representative of structural elements in lignin of the b-1, b-5, b-O-4, cinnamaldehyde and cinnamyl alcohol types were synthesized. erythro-Forms of b-1 models of the 1,2-diaryl-1,3-propanediol type were prepared by BF3-catalyzed rearrangement of chalcone epoxides and subsequent reduction of the rearrangement products with NaBH4. LÄS MER