Sökning: "lignin model compounds"
Visar resultat 1 - 5 av 32 avhandlingar innehållade orden lignin model compounds.
1. Lignin-carbohydrate complexes: Model compounds synthesis
Sammanfattning : In lignocellulose there is a recalcitrant interaction by covalent and non-covalent bonds called the lignin-carbohydrate complex. This interaction has been the subject of studies trying to unveil its chemical structure, to understand the mechanims involved in its formation and to determine its influence on practical applications such as the process of turning biomass into ethanol. LÄS MER
2. Palladium-catalyzed lignin valorization : Towards a lignin-based biorefinery
Sammanfattning : The work described in this thesis focuses on the cleavage of the β-O-4′ bond, which is the most abundant interunit linkage in the lignin polymer.In the first part, three methods based on palladium catalysis have been developed and their applicability has been verified using lignin model compounds. LÄS MER
3. Lignin Model Compounds: Synthesis, Stereochemistry and Acidolysis
Sammanfattning : Lignin model compounds representative of structural elements in lignin of the b-1, b-5, b-O-4, cinnamaldehyde and cinnamyl alcohol types were synthesized. erythro-Forms of b-1 models of the 1,2-diaryl-1,3-propanediol type were prepared by BF3-catalyzed rearrangement of chalcone epoxides and subsequent reduction of the rearrangement products with NaBH4. LÄS MER
4. Biosynthesis, interactions, and structure of native lignin
Sammanfattning : Wood biomass is an important resource in the development ofstrategies towards replacement of fossil-based materials. Woodcomprises cellulose, hemicelluloses and lignin, in amounts thatvary between species. LÄS MER
5. Production and transformation of organic compounds from renewable feedstock : Catalytic approaches
Sammanfattning : This thesis is focused on the development of strategies for lignocellulosic biomass valorization. The thesis consists of two parts.The first part of the presented work is related to the catalytic fractionation of biomass (lignin-first approach) and the production of monomeric compounds from lignocellulose. LÄS MER