Sökning: "ion association"

Visar resultat 1 - 5 av 65 avhandlingar innehållade orden ion association.

  1. 1. Characterizing ions in solution by NMR methods

    Författare :Marianne Giesecke; István Furó; Peter Griffiths; KTH; []
    Nyckelord :electrophoretic NMR; diffusion NMR; NMR imaging; ion pairing; ion association; polyethylene oxide; metal-ion complex; Li ion batteries; electrolyte characterization; Kemi; Chemistry;

    Sammanfattning : NMR experiments performed under the effect of electric fields, either continuous or pulsed, can provide quantitative parameters related to ion association and ion transport in solution.  Electrophoretic NMR (eNMR) is based on a diffusion pulse-sequence with electric fields applied in the form of pulses. LÄS MER

  3. 2. Molecular Interactions Studied by Electrophoretic and Diffusion NMR

    Författare :Fredrik Hallberg; Peter Stilbs; István Furó; Gareth Morris; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Physical chemistry; NMR; electrophoretic NMR; Ion pairing; complexation; association; diffusion; pulsed field gradient; Nafion; Spectroscopy; Spektroskopi;

    Sammanfattning : Even though electrophoretic NMR (eNMR) experiments may provide unique chemical information and have been performed for three decades, the technique is still rarely applied, mainly because several experimental sources of artifacts have to be controlled to achieve accurate results. In this thesis, new experimental setups and protocols for accurate and precise eNMR experiments are presented. LÄS MER

  4. 3. Plasma environment of an intermediately active comet : Evolution and dynamics observed by ESA's Rosetta spacecraft at 67P/Churyumov-Gerasimenko

    Författare :Elias Odelstad; Anders Eriksson; Andrew Coates; Uppsala universitet; []
    Nyckelord :Rosetta; comet; 67P; RPC-LAP; RPC-MIP; RPC-ICA; RPC-MAG; ROSINA-COPS; Langmuir probe; spacecraft potential; plasma; Churyumov-Gerasimenko; ion composition analyzer; diamagnetic cavity; ion velocity; electron temperature; ion-neutral drag; collisional coupling; wake effects; filamentation; electron cooling; plasma waves; hybrid waves; Bernstein waves; minimum variance; polarization; wavelet; density fluctuations; magnetic field oscillations; drift-cyclotron instability; asymmetric plasma and magnetic field enhancements; Fysik med inriktning mot rymd- och plasmafysik; Physics with specialization in Space and Plasma Physics;

    Sammanfattning : The subject of this thesis is the evolution and dynamics of the plasma environment of a moderately active comet before, during and after its closest approach to the Sun. For over 2 years in 2014-2016, the European Space Agency’s Rosetta spacecraft followed the comet 67P/Churyumov-Gerasimenko at distances typically between a few tens and a few hundred kilometers from the nucleus, the longest and closest inspection of a comet ever made. LÄS MER

  5. 4. Solvent–Solute Interaction : Studied by Synchrotron Radiation Based Photo and Auger Electron Spectroscopies

    Författare :Wandared Pokapanich; Olle Björneholm; Gunnar Öhrwall; Maxim Tchaplyguine; Arnaldo Naves de Brito; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Interatomic Coulombic Decay; ICD; Auger electron spectroscopy; AES; X-ray photoelectron spectroscopy; XPS; Ultra-violet spectroscopy; UPS; localized; delocalized; double ionization potential; DIP; two hole; final states; Water; H2O; Potassium chloride; KCl; Calcium chloride; CaCl2; Ammonium; NH4; Core hole; clock; lifetime; solvated; ion; alkali; halide; Coster Kronig; MAX-lab; BESSY; Liquid physics; Vätskefysik; Physics with spec. in Atomic; Molecular and Condensed Matter Physics; Fysik med inriktning mot atom- molekyl- och kondenserande materiens fysik;

    Sammanfattning : Aqueous solutions were studied using photoelectron and Auger spectroscopy, based on synchrotron radiation and a liquid micro-jet setup. By varying the photon energy in photoelectron spectra, we depth profiled an aqueous tetrabutylammonium iodide (TBAI) solution. LÄS MER

  7. 5. Ions interacting with macromolecules : NMR studies in solution

    Författare :Yuan Fang; Istvan Furo; Monika Schönhoff; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; electrophoretic NMR; diffusion NMR; specific ion effects; Hofmeister; ion binding; Kemi; Chemistry;

    Sammanfattning : Specific ion effects, identified for more than hundred years, play an important role in a wide range of phenomena and applications. Several mechanisms such as direct ion interaction with molecules have been suggested to explain these effects, but quantitative experimental evidence remains scarce. LÄS MER