Sökning: "heterogeneous surfaces"

Visar resultat 1 - 5 av 79 avhandlingar innehållade orden heterogeneous surfaces.

  1. 1. Water-Metal Surfaces : Insights from core-level spectroscopy and density functional theory

    Författare :Theanne Schiros; Anders Nilsson; John Hemminger; Stockholms universitet; []
    Nyckelord :water; hydroxyl; metal; surfaces; x-ray spectroscopy; density functional theory; bonding; fuel cell; kemisk fysik; Chemical Physics;

    Sammanfattning : Computational methods are combined with synchrotron-based techniques to analyze the structure and bonding of water and water plus hydroxyl at metal surfaces under UHV and at near-ambient conditions. Water-metal interaction plays a crucial role in a multitude of cosmic, atmospheric and biological phenomena as well as heterogeneous catalysis, electrochemistry and corrosion. LÄS MER

  3. 2. Molecular overlayers on homogeneous and heterogeneous metal surfaces studied by core-level photoemission

    Författare :Maria Smedh; Fysiska institutionen; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; photoelectron spectroscopy; core-level photoemission; electron energy loss spectroscopy; single crystal surfaces; metal surfaces; heterogeneous surfaces; adsorption; adsorbed molecules; hydrocarbons; molecular vibrations; carbon monoxide; adsorption sites; adsorption energy; diffusion; dissociation; Physics; Fysik; Fysicumarkivet A:2001:Smedh;

    Sammanfattning : The main topic of this thesis is the investigation of small molecules adsorbed on metal surfaces by means of core-level photoemission spectroscopy. The thesis consists of three parts; The first group of papers concerns the effects of internal molecular vibrations on the core-level photoemission spectra. LÄS MER

  4. 3. Development and Applications of Surface-Confined Transition Metal Complexes : Heterogeneous Catalysis and Anisotropic Particle Surfaces

    Författare :Kristofer Eriksson; Jan-Erling Bäckvall; Graham Hutchings; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; heterogeneous catalysis; anisotropic particles; protein gradients; nanoparticles; organisk kemi; Organic Chemistry;

    Sammanfattning : The main focus of this thesis has been directed towards developing novel surface-confined transition metal complexes for applications in heterogeneous catalysis and for the preparation of anisotropic particle surfaces. The first part describes the heterogenization of a homogeneous transition metal-based catalyst tetraphenyl cobalt porphyrin (CoTPP) on silicon wafers and on silica particles. LÄS MER

  5. 4. Immobilizing catalysts on textiles : case of zerovalent iron and glucose oxidase enzyme

    Författare :Mohammad Neaz Morshed; Vincent Nierstrasz; Frank Hollmann; Högskolan i Borås; []
    Nyckelord :Biocatalysts; Catalyst immobilization; Catalytic reduction; Chitosan; Dye removal; Environmental remediation; Enzyme immobilization; Glucose oxidase; Hyperbranched dendrimers; Heterogeneous catalysis; Heterogeneous bio-Fenton; Heterogeneous Fenton; Inorganic catalysts; Phenol removal; Polyester nonwoven fabric; Pathogenic bacteria removal; Plasma ecotechnology; Polyethylenimine; Textile catalyst; Textile biotechnology; Textile surface modification; Wastewater treatment; Zerovalent iron; 生物催化剂; 涤纶无纺布; 金属颗粒：铁固定化; 超支化树状大分子; 聚酰胺胺树状大分子 3-氨基丙基）; 三乙氧基硅烷; 1-硫代甘油; 聚乙烯胺; 壳聚糖; 葡萄糖氧化酶; 氧化还原酶; 酶固定化，物理吸附; 纤维催化剂; 多相催化; 抗菌纺织品; 革兰氏阳性（G ve）菌 革兰氏阴性（G-ve）菌; 类芬顿; 生物芬顿; 染料去除; 苯酚去除; 生物催化; 产业纺织品; 纺织生物技术; 纺织品表面改性; 环境治理; 废水处理; 零价铁。; Biocatalyseurs; Immobilisation de catalyseurs; Reduction de catalyseurs; Chitosane; Élimination de colorants; Assainissement de l’environnement; Immobilisation d’enzymes; Glucose oxydase; Dendrimères hyper-ramifiés; Catalyse hétérogène; Bio-Fenton hétérogène; Fenton hétérogène; Catalyseurs inorganiques; Élimination de phénols; Non-tissé Polyester; Élimination de bactéries pathogènes; Écotechnologie plasma; Polyéthylèneimine; Catalyseur textile; Biotechnologie textile; Modification de surface textile; Traitement des eaux usées; Fer zéro-valent; Biokatalysatorer; Katalysatorimmobilisering; Katalytisk reduktion; Kitosan; Avlägsnande av färgämnen; Miljösanering; Enzymimmobilisering; Glukosoxidas; Hypergrenade dendrimerer; Heterogen katalys; Heterogen bio-Fenton; Heterogen Fenton; Oorganiska katalysatorer; Fenolavlägsnande; Polyester fiberduk; Avlägsnande av patogena bakterier; Plasmaekoteknik; Polyetylenimin; Textil katalysator; Textil bioteknik; Modifiering av textilytor; Avloppsrening; Zerovalent järn; Textil och mode generell ; Textiles and Fashion General ;

    Sammanfattning : Catalytic systems are one of the most effective technologies of modern chemical processes. The system uses a molecule called ‘catalyst’ that is capable of catalyzing a reaction without being produced or consumed during the process. LÄS MER

  7. 5. Theoretical modelling of thin film growth in the B-N system

    Författare :Björn Mårlid; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Chemistry; Boron nitride; boron; theoretical modelling; DFT; surface processes; surfaces; thin films; growth ALD; Kemi; Chemistry; Kemi; Inorganic Chemistry; oorganisk kemi;

    Sammanfattning : In vapour phase deposition, the knowledge and control of homogeneous and heterogeneous reactions in connection to precursor design may lead to the deposition of the desired material; structure or phase. This thesis is a document attempting to increase the knowledge of film growth in the B-N system. LÄS MER