Sökning: "gas solid-reaction"

Hittade 5 avhandlingar innehållade orden gas solid-reaction.

  1. 1. Investigations of the Kinetics of Reduction and Reduction/Carburization of NiO-WO3 Precursors

    Författare :Hesham M. Ahmed; Seshadri Seetharaman; Ricardo Morales Estrella; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Reduction; Reduction-Carburization; Gas-solid Reactions; Kinetics; Hydrogen; Methane; Thermogravimetric analysis; Fluidized bed; Simulation; Thermal diffusivity; Thermal conductivity; Laser flash; Metallurgical process engineering; Metallurgisk processteknik; Process Metallurgy;

    Sammanfattning : Kinetic studies of reduction of the mixtures of NiO and WO3 having different Ni/(Ni+W) molar ratios in flowing hydrogen gas were investigated by means of Thermo Gravimetric Analysis (TGA), Fluidized Bed (FB) technique as well as Thermal diffusivity measurements under isothermal conditions. In the case of TGA, the reaction progress was monitored by mass loss, while evolved gas analysis by a gas chromatograph was the indicator of the reaction progress in the case of FB. LÄS MER

  2. 2. Biomass to Biofuel : Syngas Cleaning and Biomass Feedstock

    Författare :Ramiar Sadegh-Vaziri; Matthäus Bäbler; Per Alvfors; Lilian de Martin; Longcheng Liu; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Gas-Solid Reaction; ZnO Sul_dation; Outward Growth; Hollow Particles; Algae Flocculation; PBEs; Fractal Clusters; Restructuring of Clusters; Deposition of Clusters; Primary Particle Aggregation.;

    Sammanfattning : This thesis builds around the idea of a biofuel production process that is comprised of biomass production, biomass gasification, gas cleaning, and fuel production. In this work, we specifically looked into H2S removal as a part of cleaning the producer gas and flocculation of microalgae which is involved in the harvesting of microalgae after biomass production. LÄS MER

  3. 3. Hydrogen reduction route towards the production of nano-grained alloys.- Synthesis and characterization of Fe2Mo powder

    Författare :Ricardo Morales Estrella; KTH; []
    Nyckelord :Intermetallics; nano-graines; redcution kinetics;

    Sammanfattning : With a view to design processes based on gas-solid reactiontowards the production of fine-grained novel alloys andintermetallics, studies of the reduction of the mixed oxides ofFe and Mo by hydrogen towards the production of Fe-Mo alloyshave been carried out in the present work. The route offersexcellent potentials toward the bulk production of nano-grainedmaterial of tailored-composition in bulk in a green processpath. LÄS MER

  4. 4. Molecular beam study of non-adiabatic electron transfer in the Cl2+Ksurf surface reaction

    Författare :Lars Hellberg; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; harpooning; electron transfer; Cl2; surface; exo-electrons; sticking; halogen; non-adiabatic; chemiluminescence;

    Sammanfattning : Halogen molecules impinging on alkali metal surfaces constitute model systems for studies of charge transfer, dissociation dynamics and non-adiabatic energy dissipation in molecule-surface reactions. This thesis reports emission of exo-electrons and photons from the surface as a result of strong non-adabaticity in the Cl2 gas on K$^{solid}$ reaction. LÄS MER

  5. 5. Equilibrium and Kinetic Considerations in Refining of Silicon

    Författare :Jesse Franklin White; Sichen Du; Kenneth Coley; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY;

    Sammanfattning : The purity requirements for photovoltaic-grade (PV) silicon are very stringent. In PV applications, purified silicon is either doped with boron or phosphorous, so the levels of these particular elements have to be tightly controlled. LÄS MER