Sökning: "free volume"
Visar resultat 1 - 5 av 315 avhandlingar innehållade orden free volume.
1. Macroscopic Volume and Free Volume of Polymer Blends and Pressure-densified Polymers
Sammanfattning : The macroscopic volume V as a function of pressure P and temperature T is obtained from PVT measurements. PVT data is sensitive to the state of polymers and changes therein. Moreover, PVT data gives access to the free-volume fraction. LÄS MER
2. Free Volume and Mesopores in Polymer Nanocomposites
Sammanfattning : The free volume in polymers is coupled to several important physical properties, such as density, viscosity and gas diffusivity. The physical properties of polymers close to a solid surface have been shown to be significantly perturbed as compared to their bulk state. LÄS MER
3. Free Volume Determination in Polymers and Polymer Blends
Sammanfattning : The free volume of a polymer, which corresponds to the unoccupied regions accessible to segmental motions, is an important parameter for understanding and predicting many of its characteristic properties. The concept of free volume is the basis for understanding the molecular mobility in polymers. LÄS MER
4. Water diffusion and free volume in hydrophilic polymers
Sammanfattning : During moisture uptake in polymers, the diffusion of the water molecules is believed to occur via unoccupied voids. These voids are called free volume cavities and their sizes are continuously altered when the moisture content in the polymer is enhanced. LÄS MER
5. Free Volume Depth Profiling at Polymer Surfaces and Interfaces
Sammanfattning : Pulsed low energy positron beams provide a unique and non-destructive tool to depth probe the free volume of polymers at surfaces and interfaces. Since the employment of low energy positron beams in polymer research is an emerging technique, some focus in this thesis has been on extracting methods and equations needed to interpret the experimental data. LÄS MER