Sökning: "fragmentation reaction"

Visar resultat 1 - 5 av 38 avhandlingar innehållade orden fragmentation reaction.

  1. 1. Quantum Chemical Studies of Radical Cation Rearrangement, Radical Carbonylation, and Homolytic Substitution Reactions

    Författare :Daniel Norberg; Nessima Salhi-Benachenhou; Sten Lunell; Tim Clark; Uppsala universitet; []
    Nyckelord :Quantum chemistry; quantum chemistry; coupled-cluster; density functional theory; meta-GGA; reaction mechanism; potential energy surface; isomerization; fragmentation; dissociation; condensation; addition; SH2; hydrogen abstraction; iodine atom transfer; complex; weakly interacting system; hyperfine coupling constant; Kvantkemi;

    Sammanfattning : Quantum chemical calculations have been performed to investigate radical cation rearrangement, radical carbonylation, and homolytic substitution reactions of organic molecules. The rearrangement of the bicyclopropylidiene radical cation to the tetramethyleneethane radical cation is predicted to proceed with stepwise disrotatory opening of the two rings. LÄS MER

  2. 2. Materials for Hydrogen storage and synthesis of new materials by hydrogenation

    Författare :Serhiy Luzan; Alexandr Talyzin; Yaroslav Filinchuk; Umeå universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Fullerene C60; MOFs; CNTs; SWCNTs; PAHs; peapods; hydrogen; hydrogen storage; hydrogenation; adsorption; surface area; pore volume; spillover; nanoribbons; fragmentation; fysikalisk kemi; Physical Chemistry; fysik; Physics;

    Sammanfattning : The search for new materials for hydrogen storage is important for the development of future hydrogen energy applications. In this Thesis, it is shown that new materials with interesting properties can be synthesized by the reaction of hydrogen with various nanocarbon precursors. The thesis consists of two parts. LÄS MER

  3. 3. Ultrafast dynamics of small quantum systems studied using electron-ion coincidence spectroscopy

    Författare :Smita Ganguly; Synkrotronljusfysik; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; coincidence spectroscopy; photodissociation dynamics; fragmentation reaction; MOLECULAR-BEAM; Cluster fission; Astrochemistry; Carbon dioxide CO2 ; ; Adamantane;

    Sammanfattning : Studying how small quantum systems, like molecules and clusters, interact with X-rays is crucial to understanding the ultrafast processes that occur in nature on incredibly short timescales, ranging from femtoseconds to picoseconds. X-rays excite small quantum systems to unstable core hole states, leading to a cascade of phenomena, including Auger decay, nuclear rearrangement, and dissociation. LÄS MER

  4. 4. Conservation biology and genetic structure of fringe populations of the scarce heath butterfly in Sweden

    Författare :Anna Cassel; Volker Loeschcke; Uppsala universitet; []
    Nyckelord :MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; Genetics; fragmentation; genetic structure; mobility; inbreeding; habitat requirements; Lepidoptera; Genetik; Clinical genetics; Klinisk genetik; Conservation Biology; naturvårdsbiologi;

    Sammanfattning : During the past century, about 82% of meadows and pastures have been lost in Sweden, with negative consequences for their flora and fauna. An example is the scarce heath butterfly, which is one of the red-listed species threatened by such habitat loss through afforestation. LÄS MER

  5. 5. Spectroscopic Studies of Isomers Produced in Relativistic Projectile Fragmentation and In-Flight Fission

    Författare :Milena Mineva; Kärnfysik; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Projectile fragmentation; nuclear structure; isomeric states; lifetimes; production rates; Kärnfysik; isomeric ratios; Nuclear physics; Fysicumarkivet A:000; in-flight fission;

    Sammanfattning : This thesis is based on a number of experiments performed at the FRagment Separator (FRS) at the Gesellschaft für Schwerionenforschung mbH (GSI) in Darmstadt, Germany, in which heavy-ion reactions at relativistic energies have been used to produce nuclei far from stability. In April 1999 projectile fragmentation of 208Pb at 1 GeV/nucleon was used to study so called K-isomers in the neutron-rich isotopes of Lu (Z=71) to Hg (Z=80). LÄS MER