Sökning: "enthalpy of solution"

Visar resultat 1 - 5 av 43 avhandlingar innehållade orden enthalpy of solution.

  1. 1. Solid-liquid Phase Equilibria and Crystallization of Disubstituted Benzene Derivatives

    Författare :Fredrik Nordström; Åke Rasmuson; Gerard Coquerel; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Salicylic acid; m-hydroxybenzoic acid; p-hydroxybenzoic acid; salicylamide; m-aminobenzoic acid; p-aminobenzoic acid; solubility; solid-liquid equilibria; thermodynamics; activity of the solid phase; ideal solubility; activity coefficient; van t Hoff enthalpy of solution; solid state; solution properties; metastable zone width; primary nucleation; nucleation kinetics; Chemical engineering; Kemiteknik;

    Sammanfattning : The Ph.D. project compiled in this thesis has focused on the role of the solvent in solid-liquid phase equilibria and in nucleation kinetics. Six organic substances have been selected as model compounds, viz. LÄS MER

  3. 2. Structural, Kinetic and Thermodynamic Aspects of the Crystal Polymorphism of Substituted Monocyclic Aromatic Compounds

    Författare :Michael Svärd; Åke Rasmuson; Hugo Meekes; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Polymorphism; crystallization; thermodynamics; kinetics; nucleation; crystallography; solubility; phase equilibria; polymorphic transformation; solution history; metastable zone; classical theory of nucleation; two-step theory of nucleation; cluster; crystal structure prediction; lattice energy; molecular mechanics; force field; electrostatic potential; potential energy hypersurface; m-aminobenzoic acid; m-hydroxybenzoic acid; Chemical engineering; Kemiteknik;

    Sammanfattning : This work concerns the interrelationship between thermodynamic, kinetic and structural aspects of crystal polymorphism. It is both experimental and theoretical, and limited with respect to compounds to substituted monocyclic aromatics. LÄS MER

  4. 3. Microcalorimetric methods for direct measurement of solubility and solvent activity

    Författare :Dennis Berling; Biokemi och Strukturbiologi; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; enthalpy of solution; solubility; solvent fugacity; solvent activity; Isothermal calorimetry; vapour pressure; Chemistry; Kemi;

    Sammanfattning : New calorimetric methods for direct measurement of solubility and solvent activity are presented. The classical role of calorimetry for measurements of enthalpic parameters is abandoned and the technique is instead used for assessing thermodynamic quantities related to the chemical potential of a substance in a solution. LÄS MER

  5. 4. Ethyl(hydroxyethyl)cellulose and Some Model Uncharged Polymers: A Calorimetric Study of Their Interaction with Surfactants in Aqueous Solution

    Författare :Geng Wang; Biokemi och Strukturbiologi; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; calorimetry; differntial scanning; isothermal titration; enthalpy; electrolyte; micelles; self-association; thermal gelling; interaction; alkyltrimethylammonium halides; sodium dodecylsulfate; surfactants; polymers; ethyl hydroxylethyl cellulose; viscosity; phase behavior; self-diffusion NMR; Physics; Fysik; Chemistry; Kemi; Fysicumarkivet A:1997:Wang;

    Sammanfattning : The interactions between uncharged polymers, e.g. ethyl(hydroxylethyl)cellulose (EHEC) and some model polymers, and ionic surfactants in aqueous solution has been studied by using isothermal titration and differential scanning calorimetry. LÄS MER

  7. 5. Thermodynamics of protein-DNA interactions

    Författare :Thomas Lundbäck; Karolinska Institutet; Karolinska Institutet; []
    Nyckelord :DNA-protein interactions; molecular recognition; thermodynamics; specificity.dehydration; salt dependence.;

    Sammanfattning : This thesis treats the molecular recognition between DNA-binding proteins and DNA and the way these interactions are affected by the surrounding water solution and dissolved solutes. The work involves studies on the thermodynamics of sequence specific DNA-binding of the human glucocorticoid receptor DNA-binding domain and the nonsequence specific DNA- binding of Sso7d from the archaeon Sulfolobus solfataricus. LÄS MER