Sökning: "enhanced intersystem crossing"

Hittade 3 avhandlingar innehållade orden enhanced intersystem crossing.

  1. 1. Energy and Electron Transfer in Porphyrin-Based Donor--Bridge--Acceptor Systems

    Författare :Kristine Kilså; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; electron transfer; electronic coupling; donor--bridge--acceptor systems; quantum mechanical calculations; enhanced intersystem crossing; ligand and solvent effects; bridge mediation; energy transfer; porphyrin;

    Sammanfattning : The photophysical properties of supramolecular donor--bridge--acceptor systems have been investigated by spectroscopic and quantum mechanical methods. The systems consist of porphyrin donor and acceptor moieties linked by bridging chromophores of varying excitation energy, and are shown to be geometrically well-defined in terms of length and rotational conformation. LÄS MER

  3. 2. Tuning of Energy and Electron Transfer Rates in Donor-Bridge-Acceptor Systems

    Författare :Karin Pettersson; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; electron transfer; electronic coupling; paramagnetic species; superexchange; Donor-bridge-acceptor system; spectroscopy.; porphyrin; sequential electron transfer; Förster energy transfer; energy transfer;

    Sammanfattning : The intramolecular processes of Donor-Bridge-Acceptor (D-B-A) systems have been investigated by spectroscopic methods. The systems consist of porphyrin donors and acceptors linked by oligo-p-phenyleneethynylene bridges. LÄS MER

  4. 3. Theoretical Studies on Magnetic and Photochemical Properties of Organic Molecules

    Författare :Xing Chen; Olav Vahtras; Zilvinas Rinkevicius; Ian Carmichael; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES;

    Sammanfattning : The present thesis is concerned with the theoretical studies on magnetic and photochemical properties of organic molecules. The ab initio and first principles theories were employed to investigate the vibrational effects on the isotropic hyperfine coupling constant (HFCC) known as the critical parameter in electron paramagnetic resonance spectrum, the theoretical simulations of the vibronically resolved molecular spectra, the photo-induced reaction mechanism of α-santonin and the spin-forbidden reaction of triplet-state dioxygen with cofactor-free enzyme. LÄS MER