Sökning: "disproportionation"

Visar resultat 1 - 5 av 17 avhandlingar innehållade ordet disproportionation.

  1. 1. Some factors affecting the amount of residual phase lignin during kraft pulping

    Författare :Mikael E. Lindström; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Deligniflcation; Residual phase lignin; Hydrogensulfide ion; Hydroxide ion; Polysulfides; Ionic strength; Temperature; Lignin; Kraftpulping; Selectivity; viscosity; Kappa number; chemical degradation; Disproportionation; Cellulose and paper engineering; Cellulosa- och pappersteknik;

    Sammanfattning : The amount of lignin which needs to be removed according to the slow residual delignification phase in kraft pulping, i e residual phase lignin, has been studied as a function of the process conditions. The variebles studied were the concentrations of hydroxide ions, hydrogensulfide ions, sodium ions (ionic strength) and temperature. LÄS MER

  3. 2. Chemical Processes at the Water-Manganite (γ-MnOOH) Interface

    Författare :Madeleine Ramstedt; Staffan Sjöberg; Per Persson; Lars Lövgren; Steven A. Banwart; Umeå universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Inorganic chemistry; manganite; γ-MnOOH; mineral surface; acid-base properties; adsorption; Cd II ; N- phosphonomethyl glycine; glyphosate; PMG; surface complex; dissolution; disproportionation; XPS; EXAFS; infrared spectroscopy; SEM; AFM; potentiometry; electrophoresis; Oorganisk kemi; Inorganic chemistry; Oorganisk kemi; oorganisk kemi; Inorganic Chemistry;

    Sammanfattning : The chemistry of mineral surfaces is of great importance in many different areas including natural processes occurring in oceans, rivers, lakes and soils. Manganese (hydr)oxides are one important group to these natural processes, and the thermodynamically most stable trivalent manganese (hydr)oxide, manganit (γ-MnOOH), is studied in this thesis. LÄS MER

  4. 3. Nucleoside phosphoramidates and related compounds : development of synthetic methods based on H-phosphonate chemistry

    Författare :Inger Kers; Wojciech J. Stec; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Organic Chemistry; organisk kemi;

    Sammanfattning : In this thesis, studies directed towards development of new synthetic methods for the preparation of nucleotide analogues of potential medical value as antisense, antigene or antiviral agents, are described.Two methods for synthesis of N3'->P5' and P3'->N5' phosphoramidate analogues with the nitrogen atom in bridging position of the internucleotide linkage was developed. LÄS MER

  5. 4. Sorption and Surface Complexation of Plutonium

    Författare :Mattias Olsson; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES;

    Sammanfattning : Plutonium is a constituent of spent nuclear fuel. As such, its behavior in contact with the surfaces of solids is of interest. This behavior will affect the migration of plutonium in case it is released into the environment. The chemistry of plutonium is rather complex. LÄS MER

  7. 5. Correlated materials : models and methods

    Författare :Hugo Strand; Göteborgs universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; correlated electrons; Hubbard model; multiband Hubbard model; dynamical mean field theory; exact diagonalization; Landau theory; Mott metal-insulator transition; Gutzwiller method; many-body point group symmetry; ironchalcogenides; Kanamori interaction; Slater-Condon interaction;

    Sammanfattning : This thesis encompass a series of studies on methods and models for electron systems with local interactions, relevant for correlated materials. The first study focus on the canonical model for local correlation, the Hubbard model. LÄS MER