Sökning: "dihalo-analogues"

Hittade 2 avhandlingar innehållade ordet dihalo-analogues.

1. 1. Synthesis and applications of analogues of Tröger's base as molecular tubes, receptor and ligands

   Författare :Anna Hansson; Centrum för analys och syntes; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Organisk kemi; Organic chemistry; bis-crown ether analogue; molecular recognition; molecular tubes; Tröger s base; dihalo-analogues;

   Sammanfattning : Tröger’s base was synthesized for the first time in 1887. The molecule is rigid, C2-symmetric and has a 90° angle, forming a chiral hydrophobic pocket. In this thesis, the synthesis of new analogues of Tröger’s base is described. 2- and 3-halo-substituted anilines have for the first time been condensed to Tröger’s base analogues. LÄS MER

3. 2. Making Analogues of Tröger's Base – Fused oligomers, endo/exo isomers and twisted amides

   Författare :Josep Artacho Ruiz; Centrum för analys och syntes; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES;

   Sammanfattning : The centenarian Tröger’s base (TB) was envisaged as scaffold for the construction of tubular-shaped cleft molecules due to its the remarkable structural properties. This endeavor started with the synthesis of the three possible diastereomers of a linear symmetrically fused tris-TB analogue, the anti-anti, the syn-syn, and the syn-anti. LÄS MER