Sökning: "deprotonation"

Visar resultat 1 - 5 av 31 avhandlingar innehållade ordet deprotonation.

  1. 1. Interface-Assisted Perovskite Modulations for High-Performance Light-Emitting Diodes

    Författare :Chaoyang Kuang; Feng Gao; Sai Bai; Niclas Solin; Olle Inganäs; Mingjian Yuan; Linköpings universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Metal halide perovskite; Light-emitting diodes; Deprotonation; Interfacial reaction; Additive; Molecular interactions; Metall-halid-perovskiter; Lysdioder; Deprotonering; Gränsytegenererade reaktion; Tillsatsämnen; Molekylära interaktioner;

    Sammanfattning : Metal halide perovskites have emerged as a class of promising materials for a wide range of optoelectronic devices. Compared with traditional inorganic and organic semiconductors, perovskite materials can be easily processed via solution-based techniques at low temperatures and exhibit high photo-luminescence efficiency, outstanding colour purity, and superior charge transport properties, showing great promise for cost-effective and high-performance light-emitting diodes (LEDs). LÄS MER

  3. 2. Synthesis and Applications of P-chirogenic Phosphine Boranes

    Författare :Magnus Johansson; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; cytisine; gold I catalysis lipase; P-chirogenic; desymmetrization; phosphine; enantioselective cyclopropanation. enantioselective deprotonation; chirality; asymmetric synthesis; borane;

    Sammanfattning : AbstractThis thesis reports the independent synthesis of both enantiomers of P-chirogenic phosphine ligands and the building blocks thereof, which are suitable for parallel synthesis efforts and for the generation of more diverse libraries of P-chirogenic compound. The use of P-chirogenic phosphine boranes in transition metal-catalyzed reactions, such as palladium-catalyzed allylic alkylation and amination, is also described. LÄS MER

  4. 3. Regulation of Proton Coupled Electron Transfer from Amino Acids in Artificial Model Systems: A Mechanistic Study

    Författare :Martin Sjödin; Leif Hammarström; Jan Davidsson; G. Daniel Nocera; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Physical chemistry; Proton Coupled Electron Transfer; Tyrosine; Tryptophan; Electron Transfer; Hydrogen bond; Photosystem II; Proton transfer; Radical protein; Fysikalisk kemi; Physical chemistry; Fysikalisk kemi;

    Sammanfattning : Amino acid radicals are key redox intermediates in several natural enzymes including Cytochrome c peroxidase, DNA photolyase, ribonucletide reductase, cytochrome c oxidase and photosystem II. Electron transfer from amino acids is often coupled to deprotonation and this thesis concerns the coupling of electron transfer from tyrosine and tryptophan to trisbipyridineruthenium(III) with deprotonation in model complexes. LÄS MER

  5. 4. Proton-Coupled Electron Transfer from Hydrogen-Bonded Phenols

    Författare :Tania Irebo; Leif Hammarström; James M. Mayer; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Proton-coupled electron transfer; phenol oxidation; hydrogen bonds; artificial photosynthesis; promoting vibrations; proton transfer; laser flash-quench; transient absorption.; Physical chemistry; Fysikalisk kemi; Fysikalisk kemi; Physical Chemistry;

    Sammanfattning : Proton-coupled electron transfer (PCET) is one of the elementary reactions occurring in many chemical and biological systems, such as photosystem II where the oxidation of tyrosine (TyrZ) is coupled to deprotonation of the phenolic proton. This reaction is here modelled by the oxidation of a phenol covalently linked to a Ru(bpy)32+-moitey, which is photo-oxidized by a laser flash-quench method. LÄS MER

  7. 5. Surface reactions of natural illites from different origins

    Författare :Wenxin Liu; Luleå tekniska universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Chemistry of Interfaces; Gränsytors kemi;

    Sammanfattning : Studies of natural illites from different origins were performed, including surface acid-base properties, determination of total inorganic carbonates, and spectroscopic investigations of chemical and structural nature as well as alterations of surface properties by acid-base titration. Using surface complexation model, the fitting results showed that the acid-base behavior of aqueous illite surfaces was dominated by deprotonation procedure. LÄS MER