Sökning: "cyclic degradation"

Visar resultat 1 - 5 av 71 avhandlingar innehållade orden cyclic degradation.

  1. 1. On cyclic accumulation models for degradation of railway foundations

    Författare :Hossein Tahershamsi; Chalmers tekniska högskola; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Natural soft clay; Global Sensitivity Analysis; Sobol method; Experimental design; Rate-dependent models; Cyclic accumulation models; Cyclic degradation; Uncertainty analysis;

    Sammanfattning : The degradation of railway foundations due to the repeated loading of traffic induces maintenance and safety obligations for the track operator. One major contributor to track degradation is the accelerated settlement rates in soft soils below the track that lead to alignment issues, especially at stiffness transitions. LÄS MER

  2. 2. Controlling Polylactide Degradation through Stereocomplexation and Lactic Acid Based Additives

    Författare :Sofia Regnell Andersson; Minna Hakkarainen; Ann-Christine Albertsson; Marek Kowalczuk; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Polylactide; stereocomplex; plasticizer; degradation; degradation products; ESI-MS;

    Sammanfattning : The successful use of degradable materials in new applications depends on our ability to control the degradation process. A number of aspects need to be evaluated including degradation rate, the onset of degradation and the nature, formation and release of degradation products. LÄS MER

  3. 3. Tuning the polylactide hydrolysis rate without introducing new migrants

    Författare :Sofia Regnell Andersson; Minna Hakkarainen; Karin Jacobson; Ulrika Edlund; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; polylactide; sterocomplex; plasticizer; degradation; degradation products; ESI-MS; Biochemistry; Biokemi; Polymer chemistry; Polymerkemi;

    Sammanfattning : The possibility to control and tune the hydrolytic degradation rate of polylactide without introducing any new degradation products was investigated by subjecting polylactide with cyclic or linear oligolactic acid additives, and a stereocomplex between the L- and D-enantiomers of polylactide to hydrolytic degradation at 37 and 60 °C for up to 39 weeks. The degradation was monitored by measuring mass loss, molar mass changes, water uptake, changes of surface structure, crystallinity and thermal properties. LÄS MER

  4. 4. Solid-Phase Microextraction in Polymer Analysis - Extraction of Volatiles from Virgin and Recycled Polyamide 6.6

    Författare :Mikael Gröning; Minna Hakkarainen; Stephen Kelley; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Chemistry; polymer; polyamide 6.6; volatiles; emissions; degradation; quantitation; Kemi; Chemistry; Kemi;

    Sammanfattning : The extraction and quantitative analysis of low molar mass compounds in polymers is an analytical challenge. It is also important from a practical point of view because the low molar mass compounds in time will migrate from the polymers into the surrounding environment. LÄS MER

  5. 5. Migration from plastic food packaging during microwave heating

    Författare :Jonas Alin; Minna Hakkarainen; Sahar Al-Malaika; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; migration; food packaging; microwave; degradation; food simulant; antioxidant;

    Sammanfattning : Microwave heating of food has increased rapidly as a food processing technique. This increases the concern that chemicals could migrate from food packaging to food. The specific effect of microwave heating in contrast to conventional heating on overall and specific migration from common plastic food storage boxes was studied in this work. LÄS MER