Sökning: "crystallization"

Visar resultat 6 - 10 av 251 avhandlingar innehållade ordet crystallization.

  1. 6. Physical properties and crystallization of theophylline co-crystals

    Författare :Shuo Zhang; Åke Rasmuson; Per Svensson; Mårten Behm; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Theophylline; oxalic acid; glutaric acid; maleic acid; co-crystal; decomposition temperature; melting temperature; solubility; crystallization; Molecular transport processes in chemical process engineering; Molekylära transportprocesser i kemisk processteknik;

    Sammanfattning : This work focuses on the physical properties and crystallization of theophyline co-crystals. Co-crystals of theophylline with oxalic acid, glutaric acid and maleic acid have been investigated. The DSC curves of these co-crystals show that their first endothermic peaks are all lower than the melting temperature of theophylline. LÄS MER

  3. 7. Crystallization of Metal Fluoride Hydrates from Mixed Acid Solutions

    Författare :Kerstin Forsberg; Åke Rasmuson; Alison Lewis; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; crystallization; crystal growth; b-FeF3.3H2O; iron fluoride trihydrate; CrF3.3H2O; pickling; pickle bath; hydrofluoric acid; nitric acid; stainless steel; Chemical engineering; Kemiteknik;

    Sammanfattning : In this work crystal growth and nucleation of b-FeF3×3H2O and crystallization of chromium (III), iron (III) and nickel (II) fluoride hydrates from mixed acid (1-3 mol/kg HNO3 and 1-6 mol/kg free HF) have been investigated. The solubility of b-FeF3×3H2O has been determined in solutions of different hydrofluoric acid (1-7mol/ kg) and nitric acid (0-7mol/ kg) concentrations at 30, 40 and 50°C. LÄS MER

  4. 8. Investigations intothe crystallization of butyl paraben

    Författare :Huaiyu Yang; Åke Rasmuson; Mårten Behm; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Butyl paraben; Solubility; Thermodynamic; Activity; Activity coefficient; Second order correlation; Liquid-liquid phase separation; Ternary phase diagram; Nucleation; Induction time; Free energy; Interfacial energy; Nuclei critical radius Cooling crystallization; Evaporation crystallization; Chemical engineering; Kemiteknik;

    Sammanfattning : In thisproject, solubility of butyl paraben in 7 puresolvents and 5 ethanol aqueous solvents has been determined at from 1 ℃to 50 ℃. Thermodynamic properties of butyl paraben have been measured by DifferentialScanning Calorimetey. LÄS MER

  5. 9. Process modeling of semibatch reaction crystallization

    Författare :Marie Ståhl; Åke Rasmuson; Hermann J.M. Kramer; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Reaction crystallization; benzoic acid; nucleation; growth; kinetics; growth rate dispersion; Chemical physics; Kemisk fysik;

    Sammanfattning : This thesis aims at increasing the fundamental understanding of reaction crystallization by modeling, simulations and parameter estimation. Benzoic acid is used as the model compound. LÄS MER

  7. 10. Crystallization of chiral compounds-Possibilities and limitations for resolution by direct crystallization

    Författare :Veronica Profir; KTH; []
    Nyckelord :metastable racemate; nucleation; solvent effect; solubility; direct crystallization; in situ IR spectroscopy; multivariate calibration;

    Sammanfattning : .... LÄS MER