Sökning: "core-excited state"

Visar resultat 16 - 20 av 30 avhandlingar innehållade orden core-excited state.

1. 16. Formation and fragmentation dynamics of superexcited molecules

   Författare :Ken Yoshiki Franzén; KTH; []
   Nyckelord :;

   Sammanfattning : A series of experimental studies on superexcited smallmolecules have been performed giving new information on theformation and fragmentation dynamics of small superexcitedmolecules. Highly monochromatized synchrotron radiation hasbeen applied in the 5-30 eV energy region, corresponding tovalence shell excitation, and in the 60-600 eV region,corresponding to core shell excitation, to reach these neutralstates above the ionization potential. LÄS MER

3. 17. Infrared - X-ray pump probe spectroscopy

   Författare :Viviane Costa Felicissimo; Faris Gelmukhanov; KTH; []
   Nyckelord :MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; Biochemistry; Biokemi; Biochemistry; Biokemi;

   Sammanfattning : The present thesis concerns theoretical studies of molecular interactions investigated by infrared and X-ray spectroscopic techniques, with emphasis on using the two technologies combined in pump probe experiments. Three main types of studies are addressed: the use of near-edge X-ray absorption fine structure spectra (NEXAFS) to manifest through-bond and through-space interactions; the role of hydrogen bonding on the formation of X-ray photoelectron spectra as evidenced by simulations of the water dimer; and the development of theory, with sample applications, for infrared X-ray pump probe spectroscopy - the main theme of the thesis. LÄS MER

4. 18. Aqueous Solutions as seen through an Electron Spectrometer : Surface Structure, Hydration Motifs and Ultrafast Charge Delocalization Dynamics

   Författare :Niklas Ottosson; Svante Svensson; Olle Björneholm; Gunnar Öhrwall; Clemens Heske; Uppsala universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Water; Aqueous solutions; Ions; Molecular Hydration; Electron dynamics; Atmospheric Chemistry; Hydrolysis; Acid-Base Chemistry; Interatomic Coulombic Decay; ICD; Liquid Micro-Jet; X-ray Photoelectron Spectroscopy; XPS; Auger Electron Spectroscopy; AES; MAX-lab; BESSY; Physics; Fysik; Physics with spec. in Atomic; Molecular and Condensed Matter Physics; Fysik med inriktning mot atom- molekyl- och kondenserande materiens fysik;

   Sammanfattning : In spite of their high abundance and importance, aqueous systems are enigmatic on the microscopic scale. In order to obtain information about their geometrical and electronic structure, simple aqueous solutions have been studied experimentally by photo- and Auger electron spectroscopy using the novel liquid micro-jet technique in conjunction with synchrotron radiation. LÄS MER

5. 19. Studies of Molecular and Cluster Fragmentation Using Synchrotron Radiation: Measurements and Models

   Författare :Andreas Lindgren; Synkrotronljusfysik; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Atom- och molekylärfysik; Atomic and molecular physics; photoionization; synchrotron radiation; localized excitation; electron-ion coincidence; induced alignment; clusters; molecules; core excitation; mass spectroscopy; fragmentation; dissociation;

   Sammanfattning : A new spectrometer for studying photoinduced fragmentation has been designed and commissioned. The instrument produces a detailed view of the energy and angular emission of fragments, which in the case of small molecules can be related to their geometry at the moment of dissociation. LÄS MER

7. 20. Resonant Soft X-Ray Emission Spectroscopy of Vanadium Oxides and Related Compounds

   Författare :Thorsten Schmitt; Joseph Nordgren; Laurent Duda; Stefan Eisebitt; Uppsala universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Physics; vanadium oxides; Li-battery; cathode materials; copper oxides; soft X-ray absorption; soft X-ray emission; resonant inelastic X-ray scattering; cluster model calculations; Fysik; Physics; Fysik;

   Sammanfattning : This thesis addresses the electronic structure of vanadium and copper oxides using soft X-ray absorption (SXA) spectroscopy and resonant inelastic X-ray scattering (RIXS) at high brightness synchrotron radiation sources. In RIXS incident photons, tuned to the energy of specific absorption resonances, are inelastically scattered leaving behind a low energy valence excitation in the system studied. LÄS MER