Sökning: "complex salt"

Visar resultat 6 - 10 av 126 avhandlingar innehållade orden complex salt.

1. 6. Phase Equilibria and Structures of Oppositely Charged Polymers and Surfactants in Water

   Författare :Anna Svensson; Fysikalisk kemi; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; self diffusion; PFG NMR; hexagonal; cubic Pm3n; liquid crystals; SAXS; polymer; counterion; complex; polyelectrolyte; surfactant; Monte Carlo simulations; Physical chemistry; Fysikalisk kemi;

   Sammanfattning : A new approach to the study of aqueous mixtures of oppositely charged polymers and surfactants has been introduced. Pure polyion-surfactant ion complex salts have been synthesized and used as the point of departure. The elimination of the simple ions reduces the number of components in the mixtures, thus greatly simplifying the system. LÄS MER

3. 7. Phase Behavior and Solution Properties of Aqueous Polyion-Surfactant Ion Systems

   Författare :John Janiak; Fysikalisk kemi; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Polymer-surfactant association; complex salt; nonionic surfactant; poly acrylic acid ; poly methacrylic acid ; copolymer; polymeric counterion; decyl betainate; phase behavior; solubilization; mixed micelle; hydrolysis; release; liquid crystal; nanoparticles; thermosresponsive; C12E8; C12E5;

   Sammanfattning : Polyelectrolytes and oppositely charged surfactants interact through attractive electrostatic forces, which in many cases lead to phase separation already at low total concentrations. During the past 10-15 years investigations of these systems have been simplified through the use of complex salts that consist of surfactants with polymeric counterions in a 1:1 charge stoichiometry (no excess simple counterions present). LÄS MER

4. 8. Structure and Phase Stability of Polyelectrolyte-Macroion Solutions

   Författare :Marie Skepö; Kemiska institutionen; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Physical chemistry; Fysikalisk kemi; hydrophobicity; spatially distributed interaction sites; protein-polymer interaction; Monte Carlo Simulations; redissolution; phase separation; cluster; complex; Polyelectrolytes; macroions;

   Sammanfattning : Polyelectrolytes are polymers bearing ionisable groups, which, in polar solvents, can dissociate into charged polymer chains (polyelectrolytes) and small counterions. In aqueous solutions, polyelectrolytes interact strongly with other macroions and in particular they tend to associate with objects of opposite charge and form complexes. LÄS MER

5. 9. Phase Phenomena in Polymer Networks : Empirical Studies on the Influence of Hydrophobicity, Charge Density and Crosslinks on Macroion-Induced Phase Transitions in Polyelectrolyte Gels

   Författare :Martin Andersson; Per Hansson; Lennart Piculell; Uppsala universitet; []
   Nyckelord :MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; Gel; microgel; microsphere; polystyrenesulfonate; polyacrylate; polyacrylicacid; DoTAB; DoTAC; CTAB; CTAC; network; polyelectrolyte; complex salt; self assembly; phase behaviour; hysteresis; thermodynamic; core-shell; lysozyme; cytochrome c; microscopy; micromanipulator; elastomer; elastic; protein; surfactant; phase behaviour; sorting; PHARMACY; FARMACI; Physical chemistry; Fysikalisk kemi;

   Sammanfattning : The thesis concerns polyelectrolyte gels in contact with oppositely charged proteins and surfactant micelles, and includes of four papers (I-IV). In paper I confocal Raman spectroscopy was introduced as a method to trace micelles and investigate the structure of gel-surfactant complexes, in phase separated gel spheres. LÄS MER

7. 10. Electrostatic Interactions in Complex Liquids : A Thermodynamic Analysis Based on the Poisson-Boltzmann Equation and the Flexible Surface Model

   Författare :Ingemar Carlsson; Fysikalisk kemi; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; AOT; AerosolOT; ionic surfactant; spontaneous curvature; bending modulus; bending energy; Helfrich curvature energy; fluid membrane; complex liquid; flexible surface model; micelle; counterion; Poisson-Boltzmann equation; cell model; L3 phase; sponge phas; Physical chemistry; Fysikalisk kemi;

   Sammanfattning : The aim of this study was to analyse physico-chemical properties of some complex liquids using the Poisson-Boltzmann (PB) cell model; to extend the theory to cover bilayer systems with complex global geometry; finally to apply this new extended model to such bilayer systems. The PB cell model provides a practical tool to examine counterion association and phase behaviour for structures of simple geometries; cylindrical and spherical. LÄS MER