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Visar resultat 1 - 5 av 52 avhandlingar som matchar ovanstående sökkriterier.

1. 1. Electrochemical Reactions in Polymer Electrolyte Fuel Cells

   Författare :Maria Wesselmark; Svein Sunde; KTH; []
   Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Fuel cell; model electrodes; oxygen reduction; methanol oxidation; formic acid oxidation; hydrogen oxidation; CO oxidation; degradation; tungsten oxide; carbon support; Bränslecell; modellelektroder; syrgasreduktion; metanoloxidation; myrsyraoxidation; vätgasoxidation; CO oxidation; degradering; wolfram oxid; kolsupport; Chemical engineering; Kemiteknik;

   Sammanfattning : The polymer electrolyte fuel cell converts the chemical energy in a fuel, e.g. hydrogen or methanol, and oxygen into electrical energy. The high efficiency and the possibility to use fuel from renewable sources make them attractive as energy converters in future sustainable energy systems. LÄS MER

3. 2. Structural, Electronic and Reactive Properties of Pentapyridyl - Base Metal Complexes : Relevance for Water Oxidation Catalysis

   Författare :Manuel Boniolo; Johannes Messinger; Antoni Llobet; Uppsala universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Water oxidation; Base metal complexes; Redox potential; Spin crossover; Magnetic anisotropy; Chemistry with specialization in Molecular Biomimetics; Kemi med inriktning mot molekylär biomimetik;

   Sammanfattning : The rationalization of chemical-physical proprieties of transition metal complexes is fundamental in order to understand and tune their reactivity. In this thesis, a systematic investigation of the geometrical and electronic properties of [M(Py5OH)Cl]+ complexes (M= Mn, Fe, Co, Ni) has been performed, and their ability to act as molecular water oxidation catalysts has been probed. LÄS MER

4. 3. Computational Studies on Homogeneous Water Oxidation Catalysts

   Författare :Ge Li; Mårten S. G. Ahlquist; Moyses Araujo; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Computational studies; homogeneous; water oxidation catalysts; ruthenium; iron; mechanisms; Teoretisk kemi och biologi; Theoretical Chemistry and Biology;

   Sammanfattning : To combat the increasing energy demand and climate change, artificial photosynthesis is a promising approach to producing renewables by storing energy into chemicals and fuels. Water oxidation, responsible for offering electrons and protons to the reduction reactions, suffers from slow kinetics. LÄS MER

5. 4. Innovative process solutions towards recycling of salt cake from secondary aluminum smelting

   Författare :Peng Li; Lidong Teng; Sankaran Subramanian; KTH; []
   Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Thermal diffusivity; Model; Solubility; CO2; AlN; Crystals; Hydrolysis; Enhance; Hinder; Leaching; Absorption; Synthesis; SiMgAlON; Oxidation; Arctan; Activation energy; Mullite; Liquid; Crystallization.; SRA - Production; SRA - Produktion;

   Sammanfattning : To offer better solutions for the recycling of salt cake from secondary aluminum melting, several innovative investigations were carried out based on hydrometallurgical and pyrometallurgical views.Thermal diffusivity measurements as a function of temperature on salts-Al composites having various compositions (0, 2, 4, 6, 8, 10, 12wt pct metallic Al) were carried out. LÄS MER

7. 5. Chlorine Induced Corrosion in Biomass and Waste Fired Boilers: Laboratory and Field Investigations

   Författare :Nicklas Folkeson; Chalmers tekniska högskola; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; austenitic; chloride; biomass; high temperature corrosion; ferritic; waste; steel;

   Sammanfattning : The fireside corrosion in biomass and waste fired boilers is widely believed to arise from the presence of chlorine-containing compounds in the fuels. Although many researchers have studied the influence of such compounds on the high temperature corrosion of various steels, the mechanisms underlying chlorine-induced corrosion are still poorly understood. LÄS MER