Sökning: "chloride oxidation"

Visar resultat 1 - 5 av 47 avhandlingar innehållade orden chloride oxidation.

  1. 1. Electrochemical Reactions in Polymer Electrolyte Fuel Cells

    Författare :Maria Wesselmark; Svein Sunde; KTH; []
    Nyckelord :ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; Fuel cell; model electrodes; oxygen reduction; methanol oxidation; formic acid oxidation; hydrogen oxidation; CO oxidation; degradation; tungsten oxide; carbon support; Bränslecell; modellelektroder; syrgasreduktion; metanoloxidation; myrsyraoxidation; vätgasoxidation; CO oxidation; degradering; wolfram oxid; kolsupport; Chemical engineering; Kemiteknik;

    Sammanfattning : The polymer electrolyte fuel cell converts the chemical energy in a fuel, e.g. hydrogen or methanol, and oxygen into electrical energy. The high efficiency and the possibility to use fuel from renewable sources make them attractive as energy converters in future sustainable energy systems. LÄS MER

  2. 2. Structural, Electronic and Reactive Properties of Pentapyridyl - Base Metal Complexes : Relevance for Water Oxidation Catalysis

    Författare :Manuel Boniolo; Johannes Messinger; Antoni Llobet; Uppsala universitet; []
    Nyckelord :NATURAL SCIENCES; NATURVETENSKAP; NATURVETENSKAP; NATURAL SCIENCES; Water oxidation; Base metal complexes; Redox potential; Spin crossover; Magnetic anisotropy; Chemistry with specialization in Molecular Biomimetics; Kemi med inriktning mot molekylär biomimetik;

    Sammanfattning : The rationalization of chemical-physical proprieties of transition metal complexes is fundamental in order to understand and tune their reactivity. In this thesis, a systematic investigation of the geometrical and electronic properties of [M(Py5OH)Cl]+ complexes (M= Mn, Fe, Co, Ni) has been performed, and their ability to act as molecular water oxidation catalysts has been probed. LÄS MER

  3. 3. Computational Studies on Homogeneous Water Oxidation Catalysts

    Författare :Ge Li; Mårten S. G. Ahlquist; Moyses Araujo; KTH; []
    Nyckelord :NATURAL SCIENCES; NATURVETENSKAP; NATURVETENSKAP; NATURAL SCIENCES; Computational studies; homogeneous; water oxidation catalysts; ruthenium; iron; mechanisms; Teoretisk kemi och biologi; Theoretical Chemistry and Biology;

    Sammanfattning : To combat the increasing energy demand and climate change, artificial photosynthesis is a promising approach to producing renewables by storing energy into chemicals and fuels. Water oxidation, responsible for offering electrons and protons to the reduction reactions, suffers from slow kinetics. LÄS MER

  4. 4. Innovative process solutions towards recycling of salt cake from secondary aluminum smelting

    Författare :Peng Li; Lidong Teng; Sankaran Subramanian; KTH; []
    Nyckelord :ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Thermal diffusivity; Model; Solubility; CO2; AlN; Crystals; Hydrolysis; Enhance; Hinder; Leaching; Absorption; Synthesis; SiMgAlON; Oxidation; Arctan; Activation energy; Mullite; Liquid; Crystallization.; SRA - Production; SRA - Produktion;

    Sammanfattning : To offer better solutions for the recycling of salt cake from secondary aluminum melting, several innovative investigations were carried out based on hydrometallurgical and pyrometallurgical views.Thermal diffusivity measurements as a function of temperature on salts-Al composites having various compositions (0, 2, 4, 6, 8, 10, 12wt pct metallic Al) were carried out. LÄS MER

  5. 5. Critical potential and oxygen evolution of the chlorate anode

    Författare :Linda Nylén; Göran Lindbergh; Yohannes Kiros; KTH; []
    Nyckelord :ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; chlorate; chloride oxidation; oxygen evolution; critical anode potential; chromate; DSA; mass transport; RDE; Chemical engineering; Kemiteknik;

    Sammanfattning : In the chlorate process, natural convection arises thanks to the hydrogen evolving cathode. This increases the mass transport of the different species in the chlorate electrolyte. There is a strong connection between mass transport and the kinetics of the electrode reactions. LÄS MER