Sökning: "chemical kinetics"

Visar resultat 16 - 20 av 574 avhandlingar innehållade orden chemical kinetics.

  1. 16. Oxidative dissolution of UO2 by α-radiolysis

    Författare :Niklas Hansson; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; hydrogen effect; kinetics; MOX; α-radiolysis; dose rate; UO2; ε-particles;

    Sammanfattning : To prevent the spread of radiotoxic nuclides in the environment, spent nuclear fuel generated by decades of nuclear power operation must be safely stored for at least 100 000 years. The KBS-3 method is a highly developed deep geological repository concept and is the first final repository design for high-level nuclear waste to be constructed. LÄS MER

  3. 17. Char conversion kinetics and aerosol characterization in biomass gasification

    Författare :Leteng Lin; Michael Strand; Alberto Gómez-Barea; Linnéuniversitetet; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Biomass gasification; fluidized bed; char; kinetics; aerosol; APS; TEOM; Bioenergiteknik Energi- och Miljöteknik; Bioenergy Technology;

    Sammanfattning : Biomass gasification is a thermochemical conversion by partial oxidation at elevated temperature of solid biomass into a gaseous energy carrier. The product gas contains the major components CO, H2, CO2, CH4, as well as some tar and inorganic impurities and solid particles such as ash, bed material, soot and char. LÄS MER

  4. 18. Chloromethane Complexation by Cryptophanes : Host-Guest Chemistry Investigated by NMR and Quantum Chemical Calculations

    Författare :Zoltan Takacs; Jozef Kowalewski; Mikael Akke; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Host–guest complexes; inclusion phenomenon; cryptophanes; NMR; kinetics; activation energy; dipolar interaction; exchange; quantum chemical optimization; calculated chemical shifts; NOESY; cavity size; fysikalisk kemi; Physical Chemistry;

    Sammanfattning : Host–guest complexes are widely investigated because of their importance in many industrial applications. The investigation of their physico–chemical properties helps understanding the inclusion phenomenon. The hosts investigated in this work are cryptophane molecules possessing a hydrophobic cavity. LÄS MER

  5. 19. Isoconversional analysis for the prediction of mass-loss rates during pyrolysis of biomass

    Författare :Lina Norberg Samuelsson; Matthaus Babler; Rosana Moriana; Henrik Wiinikka; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; pyrolysis; biomass; kinetics; cellulose; spruce; black-liquor; model-free; isoconversional; prediction; pyrolys; biomassa; kinetik; cellulosa; gran; svartlut; model-free; isoconversional; förutsägelse; Chemical Engineering; Kemiteknik; Energy Technology; Energiteknik;

    Sammanfattning : Biomass is the only renewable carbon source that can compete with fossil energy sources in terms of production of materials, chemicals and fuels. Biomass can be transformed into charcoal, liquid and gas through pyrolysis, i.e. pure thermal decomposition. LÄS MER

  7. 20. Structural, Kinetic and Thermodynamic Aspects of the Crystal Polymorphism of Substituted Monocyclic Aromatic Compounds

    Författare :Michael Svärd; Åke Rasmuson; Hugo Meekes; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Polymorphism; crystallization; thermodynamics; kinetics; nucleation; crystallography; solubility; phase equilibria; polymorphic transformation; solution history; metastable zone; classical theory of nucleation; two-step theory of nucleation; cluster; crystal structure prediction; lattice energy; molecular mechanics; force field; electrostatic potential; potential energy hypersurface; m-aminobenzoic acid; m-hydroxybenzoic acid; Chemical engineering; Kemiteknik;

    Sammanfattning : This work concerns the interrelationship between thermodynamic, kinetic and structural aspects of crystal polymorphism. It is both experimental and theoretical, and limited with respect to compounds to substituted monocyclic aromatics. LÄS MER