Sökning: "charge-density polyelectrolytes"

Visar resultat 1 - 5 av 21 avhandlingar innehållade orden charge-density polyelectrolytes.

1. 1. Polyelectrolytes : Bottle-Brush Architectures and Association with Surfactants

   Författare :Ali Naderi; Per M. Claesson; Orlando Rojas; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Polyelectrolyte; Surfactant; Bottle-Brush Polyelectrolyte; Comb Polyelectrolyte; Non-Equilibrium State; Polymer Architecture; Adsorption; Desorption; Association; Excluded Volume; Light Scattering; SFA; AFM; QCM-D; Turbidimeter; Mica; Silica; Surface Forces; Surface and colloid chemistry; Yt- och kolloidkemi;

   Sammanfattning : This thesis has the dual purpose of raising awareness of the importance of the mixing protocol on the end products of polyelectrolyte-oppositely charged surfactant systems, and to contribute to a better understanding of the properties of bottle-brush polyelectrolytes when adsorbed onto interfaces. In the first part of this thesis work, the effects of the mixing protocol and the mixing procedure on formed polyelectrolyte-oppositely charged surfactant aggregates were investigated. LÄS MER

3. 2. Flocculation with Polyelectrolytes in Latex and Microbial Systems

   Författare :Leif Eriksson; Fysikalisk kemi; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; floc strength; shear sensitivity; fractal dimension; floc structure; patch flocculation; adhesion; bridging; flocculation; charge compensation; adsorption; ionic strength; molecular weight; charge density; Cationic polyelectrolytes; latex; bacteria; activ; Physical chemistry; Fysikalisk kemi;

   Sammanfattning : Adsorption of cationic polyelectrolytes onto polystyrene latices was studied as function of polymer chemical composition and molecular weight, polymer and surface charge density and ionic strength. The ratio between polymer charges and surface charges was close to one when distances between polymer and surface charges were equal. LÄS MER

4. 3. Electroactive Conjugated Polyelectrolytes Based on EDOT From Synthesis to Organic Electronics

   Författare :Roger Gabrielsson; Peter Konradsson; Olle Inganäs; David Mecerreyes; Linköpings universitet; []
   Nyckelord :Conjugated polyelectrolytes; Electroactive conjugated polyelectrolytes; Intrinsically conducting polyelectrolytes;

   Sammanfattning : Conjugated polyelectrolytes (CP) show interesting electrical and optical properties for organic electronics as well as for life science applications. Their possibilities of supramolecular assembly with nanowire like misfolded proteins, amyloids, as well as synthetic polypeptides or DNA forming conducting nano composites is highly interesting as being a truly bottom up approach for fabrication of OLEDs, photovoltaic’s as well as logic devices. LÄS MER

5. 4. Polyelectrolyte - Surfactant Interactions in Dilute Suspensions. A Study Based on Monte Carlo simulations and Mean-Field Calcultations

   Författare :Torsten Wallin; Fysikalisk kemi; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; aggregation number; linear charge density; chain flexibility; mean-field; calculation; simulation; Monte Carlo; cmc; cac; interaction; electrostatic; charged; micelle; polyelectrolyte; surfactant; hydrophilic; hydrophobic; Physical chemistry; Fysikalisk kemi;

   Sammanfattning : The complexation of macroions or charged micelles and oppositely charged polyelectrolytes was studied by the use of Monte-Carlo simulations and mean field calculations. The Monte-Carlo simulations were performed on a simple model system with the emphasis on the electrostatic interaction, (i) polyelectrolyte rigidity, (ii) polyelectrolyte linear charge density, (iii) surfactant tail length, and (iv) the polyelectrolyte concentration. LÄS MER

7. 5. Effects of polyelectrolyte conformation, charge density and ion specificity in polyelectrolyte and polyelectrolyte-drug interaction

   Författare :Andreas M. Hugerth; Uppsala universitet; []
   Nyckelord :MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; Pharmaceutical chemistry; Farmaceutisk kemi; Pharmaceutical chemistry; Farmaceutisk kemi; Physical and Inorganic Pharmaceutical Chemistry; fysikalisk och oorganisk farmaceutisk kemi;

   Sammanfattning : The central theme is how the structural characteristics of sulphated polyelectrolytes and theirinteraction with counter- and coions determine the degree of polyelectrolyte self-association (gelformation), interaction with oppositely charged polyelectrolyte and polyelectrolyte-amphiphilic druginteraction in protolytic solvent medium. Such knowledge is essential for understanding and regulatingthe interaction between polyelectrolytes as well as between polyelectrolytes and a drug substance in apharmaceutical formulation and for its fate in the human organism. LÄS MER