Sökning: "charge transfer reactions"

Visar resultat 6 - 10 av 69 avhandlingar innehållade orden charge transfer reactions.

  1. 6. Bridge Mediated Electron Transfer in Conjugated and Cross-Conjugated Donor-Acceptor Compounds

    Författare :Erik Göransson; Leif Hammarström; Hans-Christian Becker; Michael R. Wasielewski; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Electron transfer; Ultrafast; Long-range; Intervalence charge transfer; cross conjugation; hyperconjugation; Physical Chemistry; Fysikalisk kemi;

    Sammanfattning : Detailed understanding of electron transfer reactions is important in many aspects of chemistry, biology and solar energy conversion.The main aim of this thesis is to provide further insight into electron transfer through highly conjugated bridge structures. LÄS MER

  3. 7. Experimental studies of proton translocation reactions in biological systems : Electrogenic events in heme-copper oxidases

    Författare :Håkan Lepp; Peter Brzezinski; Thomas Nilsson; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; heme-copper oxidase; cytochrome c oxidase; nitric oxide reductase; cbb3-type oxidase; proton pumping; uncoupling; charge-transfer; electrogenic event; flow-flash; Biophysics; Biofysik; Biophysics; biofysik;

    Sammanfattning : Terminal heme-copper oxidases (HCuOs) are transmembrane proteins that catalyze the final step in the respiratory chain - the reduction of O2 to H2O, coupled to energy conservation by generation of an electrochemical proton gradient. The most extensively investigated of the HCuOs are the aa3-type oxidases, to which cytochrome c oxidase (CytcO) belongs, which uses energy released in the O2-reduction for proton pumping. LÄS MER

  4. 8. Femtosecond Dynamics and Photochemistry in Solution

    Författare :Marcus Rasmusson; Kemisk fysik; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Kemi; Chemistry; cross-correlation function; chloroiodomethane; dihalides; bromobenzene; ion pairs; solvation; vibrational relaxation; charge-transfer; tetranitromethane; electron transfer; femtosecond spectroscopy; dissociation; Photochemistry; Fotokemi; Chemical technology and engineering; Kemiteknik och kemisk teknologi;

    Sammanfattning : The reaction dynamics of several polyatomic systems have been investigated in solution by femtosecond spectroscopy. Tetranitromethane-naphtalene complexes excited in the charge-transfer band at 400 nm undergo dissociative electron transfer, resulting in three primary products: [naphthalene].+, NO2 and C(NO2)3-. LÄS MER

  5. 9. Model Studies of Electron Transfer and Reaction Dynamics at Surfaces

    Författare :Johan Strömquist; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; dissociation; desorption; oxidation; hot precursors; surface chemical reaction; chemiluminescence; surface harpooning; charge transfer; electron emission; transient mobility; non-adiabaticity;

    Sammanfattning : Charge-transfer is of key importance in many physical, chemical and biological processes, including surface reactions. This thesis consists of several theories for and model studies of surface reactions that are initiated by electron transfer between the surface to a molecule. LÄS MER

  7. 10. Electron and Energy Transfer in Supramolecular Complexes Designed for Artificial Photosynthesis

    Författare :Helena Berglund Baudin; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Physics; artificial photosynthesis; electron transfer; energy transfer; ruthenium; manganese; Fysik; Physics; Fysik; Physical Chemistry; fysikalisk kemi;

    Sammanfattning : In the society of today the need for alternative energy sources is increasing. The construction of artificial devices for the conversion of sunlight into electricity or fuel seems very attractive from an environmental point of view, since these devices are based on processes that does not necessarily generate any harmful biproducts. LÄS MER