Sökning: "charge transfer reactions"

Visar resultat 16 - 20 av 69 avhandlingar innehållade orden charge transfer reactions.

  1. 16. Synthesis of Biomimetic Systems for Proton and Electron Transfer Reactions in the Ground and Excited State

    Författare :Giovanny A. Parada; Sascha Ott; Ana Moore; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; Solar energy conversion; artificial photosynthesis; hydrogen bonds; excited state intramolecular proton transfer; tautomerization; proton-coupled electron transfer; photosensitizer; ruthenium complex.; Chemistry with specialization in Organic Chemistry; Kemi med inriktning mot organisk kemi;

    Sammanfattning : A detailed understanding of natural photosynthesis provides inspiration for the development of sustainable and renewable energy sources, i.e. a technology that is capable of converting solar energy directly into chemical fuels. This concept is called artificial photosynthesis. LÄS MER

  3. 17. Traitement de l'interaction spin-orbite en chimie quantique et application à la réactivité des complexes d'actinides

    Författare :Emmanuel Fromager; Ulf Wahlgren; Christian Teichteil; Michael Dolg; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; quantum chemistry; actinides; charge transfer reactions; spin-orbit effects; Physics; Fysik;

    Sammanfattning : The recent methodological developments and the advent of faster computers enable nowadays to investigate theoretically the chemical reactivity of heavy element complexes. As an example we can mention actinide chemistry which is involved in the separation of nuclear wastes. LÄS MER

  4. 18. Tuning electron transfer reactions by selective excitation in porphyrin-acceptor assemblies

    Författare :Mikael Andersson; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Physics; Fysik; Physics; Fysik; Physical Chemistry; fysikalisk kemi;

    Sammanfattning : This thesis concerns electron transfer reactions from different excited states in porphyrins, and the effect of changing the energy of the link connecting the donor and acceptor. Photoinduced electron transfer, and subsequent processes were studied using ultrashort laser pulses and nanosecond laser flash photolysis. LÄS MER

  5. 19. Molecular beam study of non-adiabatic electron transfer in the Cl2+Ksurf surface reaction

    Författare :Lars Hellberg; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; harpooning; electron transfer; Cl2; surface; exo-electrons; sticking; halogen; non-adiabatic; chemiluminescence;

    Sammanfattning : Halogen molecules impinging on alkali metal surfaces constitute model systems for studies of charge transfer, dissociation dynamics and non-adiabatic energy dissipation in molecule-surface reactions. This thesis reports emission of exo-electrons and photons from the surface as a result of strong non-adabaticity in the Cl2 gas on K$^{solid}$ reaction. LÄS MER

  7. 20. Photo-induced molecular processes and charge recombination reactions driven by non-adiabatic couplings

    Författare :Michael Stenrup; Åsa Larson; Horst Köppel; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; Non-adiabatic processes; Photophysics; Photochemistry; Radiationless deactivation; Conical intersections; Five-membered aromatic heterocyclic compounds; Mutual neutralization; Dissociative recombination; kemisk fysik; Chemical Physics;

    Sammanfattning : This thesis is based on a number of theoretical studies of molecular processes in which non-adiabatic effects play a crucial role. The main part is devoted to the photophysics and photochemistry of five-membered aromatic heterocyclic compounds, with particular focus on furan and thiophene. LÄS MER