Sökning: "catalytic deactivation"

Visar resultat 11 - 15 av 74 avhandlingar innehållade orden catalytic deactivation.

  1. 11. The Use of Supercritical Fluids to Reduce the Number of Phases in Catalytic Hydrogenation: The Reaction of Fatty Acid Methyl Esters to Fatty Alcohols

    Författare :Sander van den Hark; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; fatty alcohols; single phase; deactivation; mass transport; phase reduction; supercritical fluids; hydrogenation; propane; kinetics; catalysis;

    Sammanfattning : Supercritical fluids have unique properties - between those of liquids and gases - making them attractive reaction media. In this study, propane was used to change a heterogeneous catalyst from being substrate-covered in gas-liquid hydrogenation reactions into hydrogen-covered in our experiments. LÄS MER

  2. 12. Studies of Catalytic Low-Temperature CO Oxidation over Cobalt Oxide and Related Transition Metal Oxides

    Författare :Jonas Jansson; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; catalytic CO oxidation; in-situ XRD; transition metal oxides; low temperature activity; kinetic modelling; in-situ FTIR; in-situ XANES; cobalt oxide; catalyst deactivation; reaction mechanism;

    Sammanfattning : The catalytic oxidation of carbon monoxide at low temperatures is important in many applications. The use of a low temperature active catalyst may lower the emissions during the cold-start of a car, and volatile organic compounds in exhaust gases from stationary sources might be treated without the need of preheating the gas. LÄS MER

  3. 13. Deactivation of diesel oxidation catalysts

    Författare :Jonas Andersson; Chalmers tekniska högskola; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Accelerated aging: Diesel exhaust: Oxidation catalyst: Sulfur deactivation: Phosphorous poisoning: CO oxidation: Pt dispersion: Al2O3: Sintering: TEM: XPS;

    Sammanfattning : To meet the demand for heavy- and light-duty diesel vehicles on expansive markets while complying with current and future emission standards, it is necessary to reinsure the long-livety of the applied exhaust aftertreatment technology. Loss of catalytic performance may be associated with environmental as well as economical consequences. LÄS MER

  4. 14. Deactivation of emission control catalysts for heavy-duty vehicles : Impact of biofuel and lube oil-derived contaminants

    Författare :Sandra Dahlin; Lars Pettersson; Isabella Nova; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NH3-SCR; Cu-SSZ-13; V2O5-WO3 TiO2; catalyst deactivation; diesel oxidation catalyst; sulfur; phosphorus; biodiesel; heavy-duty; emission control; regeneration; alkali metals; NH3-SCR; Cu-SSZ-13; V2O5-WO3 TiO2; katalysatordeaktivering; dieseloxidationskatalysator; svavel; fosfor; biodiesel; tunga dieselmotorer; avgasrening; regenerering; alkalimetaller; Chemical Engineering; Kemiteknik;

    Sammanfattning : Catalytic emission control is used to reduce the negative impact of pollutants from diesel exhausts on our health and on the environment. For a heavy-duty truck, such a system consists of a diesel oxidation catalyst (DOC), a diesel particulate filter (DPF), a selective catalytic reduction (SCR) catalyst, and an ammonia slip catalyst (ASC). LÄS MER

  5. 15. Fluid Catalytic Cracking Catalyst Demetallization and Reactivation, Modeling of Catalytic Cracking, and Use of Microwaves to Heat Fluid Beds

    Författare :Frank J. Elvin; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; pilot plant; nickel and vanadium deposition; catalyst; reactivation; demetallization; catalytic cracking; and microwave heating; MAT; fluid bed;

    Sammanfattning : The fluid catalytic cracking unit (FCCU), the major conversion unit in an oil refinery, uses a silica-alumina zeolite catalyst to convert heavy hydrocarbons to light hydrocarbons. A small fraction of the catalyst must be continually replaced with fresh catalyst to maintain activity. LÄS MER