Sökning: "auxiliaries"

Visar resultat 6 - 10 av 22 avhandlingar innehållade ordet auxiliaries.

  1. 6. 1. Asymmetric aldol and alkylation reactions using pyrrolidine-based chiral auxiliaries 2. Syntheses of pine sawfly pheromone precursors and structurally related compounds

    Författare :Fredrik Andersson; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Chiral auxiliary; Stereoselectivity; Lewis acid; Aldol; Alkylation; Sex pheromone; Pine sawfly; Lipase; Synthesis; Chemistry; Kemi;

    Sammanfattning : .... LÄS MER

  3. 7. Stereoselective syntheses of semichemicals : Applications in ecological chemistry

    Författare :Ellen M. Santangelo; Anna-Karin Borg-Karlsson; Olov Sterner; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Organic chemistry; synthesis; semiochemical; pheromone; Lepidoptera; diene; Organisk kemi; Organic chemistry; Organisk kemi;

    Sammanfattning : This thesis describes the syntheses of semiochemicals and their applications in the development of control methods for pest insects. The compounds synthesized are divided into three groups: 1) Lepidoptera pheromones; 2) methyl substituted chiral pheromones and 3) aphid pheromones. LÄS MER

  4. 8. Development and application of new chiral -amino alcohols in synthesis and catalysis : Use of 2-azanorboryl-3-methanols as common intermediates in synthesis and catalysis

    Författare :Pedro Pinho; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Chemistry; Asymmetric synthesis; hetero-Diels-Alder reactions; chiral cyclopentyl-amines; chiral ligands and catalysts; amino alcohols; asymmetric reductions; ruthenium transfer hydrogenation; oxazaborolidines; asymmetric additions; dialkylzinc reagents; Kemi; Chemistry; Kemi; organisk kemi; Organic Chemistry;

    Sammanfattning : The development and application of unnatural amino alcohols,prepared via hetero-Diels-Alder reactions,in synthesis and catalysis is described.The studies are concerned with the [i]scope of the hetero-Diels-Alder reaction and preparation of important intermediates in the synthesis of antiviral agents,[ii ]application of amino alcohols in the ruthenium transfer hydrogenation of ketones,[iii ]use of similar precursors in the in situ generation of oxazaborolidines for reduction of ketones,and [iv] development and application of new chiral auxiliaries for dialkylzinc additions to activated imines, respectively. LÄS MER

  5. 9. Multiple Kernel Imputation : A Locally Balanced Real Donor Method

    Författare :Nicklas Pettersson; Daniel Thorburn; Susanne Rässler; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Bayesian Bootstrap; Boundary Effects; External Information; Kernel estimation features; Local Balancing; Pólya Sampling; statistik; Statistics;

    Sammanfattning : We present an algorithm for imputation of incomplete datasets based on Bayesian exchangeability through Pólya sampling. Each (donee) unit with a missing value is imputed multiple times by observed (real) values on units from a donor pool. The donor pools are constructed using auxiliary variables. LÄS MER

  7. 10. Here I am Send Me : The Historical and Long-Term Impact of Christian Missionaries in Zambia 1924-2018

    Författare :Michael Chanda Chiseni; Ekonomisk-historiska institutionen; []
    Nyckelord :SAMHÄLLSVETENSKAP; SOCIAL SCIENCES; Christian Missionaries; human capital development; education; Health; Longterm; Zambia;

    Sammanfattning : Towards the close of the nineteenth century and into the twentieth century, there was a proliferation of Christian missionaries in Africa. Upon settling in Africa, missionaries initiated and became the main providers of Western-styled education and health care. LÄS MER