Sökning: "arylcopper"

Hittade 1 avhandling innehållade ordet arylcopper.

1. 1. Homoleptic Arylcopper Complexes

   Författare :Henrik Eriksson; Chalmers tekniska högskola; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; cocrystallisation; Grignard; organocopper; bromide; thienyl; mesityl; crystal structure; synthesis; copper I ; arylcopper;

   Sammanfattning : New arylcopper complexes have been synthesised and characterised structurally. The reaction between the Grignard reagent (viph)MgBr (viph = ortho-vinylphenyl) and CuCl has been studied and two unstable mixed aryl/halide intermediates, [Mg(THF)6][Cu5(viph)2Br4]2.THF and [Mg(THF)5Cl][Cu5(viph)4Br2]. LÄS MER