Sökning: "adsorption of polyelectrolytes and surfactants"

Hittade 4 avhandlingar innehållade orden adsorption of polyelectrolytes and surfactants.

1. 1. Polyelectrolytes : Bottle-Brush Architectures and Association with Surfactants

   Författare :Ali Naderi; Per M. Claesson; Orlando Rojas; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Polyelectrolyte; Surfactant; Bottle-Brush Polyelectrolyte; Comb Polyelectrolyte; Non-Equilibrium State; Polymer Architecture; Adsorption; Desorption; Association; Excluded Volume; Light Scattering; SFA; AFM; QCM-D; Turbidimeter; Mica; Silica; Surface Forces; Surface and colloid chemistry; Yt- och kolloidkemi;

   Sammanfattning : This thesis has the dual purpose of raising awareness of the importance of the mixing protocol on the end products of polyelectrolyte-oppositely charged surfactant systems, and to contribute to a better understanding of the properties of bottle-brush polyelectrolytes when adsorbed onto interfaces. In the first part of this thesis work, the effects of the mixing protocol and the mixing procedure on formed polyelectrolyte-oppositely charged surfactant aggregates were investigated. LÄS MER

3. 2. Polyelectrolytes on Surfaces and their Complexes with Surfactants, Thermodynamics versus kinetics

   Författare :Yulia Samoshina; Fysikalisk kemi; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Fysikalisk kemi; Polymer technology; Physical chemistry; SDS; amphiphilic polyelectrolytes; ellipsometry; reversibility; kinetics of adsorption; polyelectrolytes at solid-liquid interface; polyelectrolyte-oppositely charged surfactant complexes; biopolymers; Polymerteknik;

   Sammanfattning : The interfacial properties of polyelectrolytes, mainly cationic with various content of amphiphilic groups, and their complexes with an oppositely charged surfactant, sodium dodecyl sulfate (SDS), have been investigated using time-resolved ellipsometry. This thesis focuses on the kinetics and reversibility aspects of polymer adsorption and the control of the adsorption by regulating the electrostatic interactions. LÄS MER

4. 3. Structure-Property Relationships of Surfactants at Interfaces and Polyelectrolyte-Surfactant Aggregates

   Författare :Mikael Kjellin; KTH; []
   Nyckelord :nonionic surfactant; sugar surfactant; poly ethylene oxide ; amide; ester; polyelectrolyte; SDS; hydrophobic surface; glass surface; mica; adsorption; aggregation; micelle size; surface forces; wetting; dynamic surface tension; NMR; TRFQ; SANS; SAXS; ;

   Sammanfattning : The first part of this thesis is concerned with thestructure-property relationships in nonionic surfactantsystems. The main aim was to investigate how the surfactantstructure influences the adsorption at interfaces andinteractions between surfactant coated interfaces. LÄS MER

5. 4. Surface force studies of association phenomena at solid-liquid interfaces

   Författare :Andra Dedinaite; KTH; []
   Nyckelord :;

   Sammanfattning : The main topics of this thesis, association phenomena inbulk and at solid-liquid interfaces in polar and non-polarmedia, were studied by a range of methods. Direct forcemeasurements employing the interferometric surface forceapparatus (SFA) was the chief technique. LÄS MER