Sökning: "a-keto thioamides"

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  1. 1. Synthesis of N-Containing Compounds: Development of Methodology and its Application in Total Synthesis

    Författare :Lu Yu; Centrum för analys och syntes; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; a-keto amides; enamine catalysis; pyrrolidine; TEMPO; a-keto thioamides; a-keto amidines; a-amino-b-hydroxy ester; asymmetric transfer hydrogenation; alexine; dynamic kinetic resolution; hydroamination; 1; 2-diamines; enamines; copper;

    Sammanfattning : This thesis aims to develop new synthetic methods and explore the possibilities to apply it in the total synthesis of natural products.Chapter 2 deals with a mild procedure for the synthesis of a-keto amides by a-oxidation of the corresponding aketo amines mediated by pyrrolidine and TEMPO. LÄS MER