Sökning: "Transition rate"

Visar resultat 11 - 15 av 468 avhandlingar innehållade orden Transition rate.

  1. 11. Boundary layer streaks as a novel laminar flow control method

    Författare :Sohrab Sattarzadeh Shirvan; Jens H. M. Fransson; Edward B. White; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; boundary layer stability; laminar to turbulent transition; laminar flow control; drag reduction; Tollmien-Schlichting waves; oblique waves; streaky boundary layers; miniature vortex generators; discrete suction;

    Sammanfattning : A novel laminar flow control based on generation of spanwise mean velocity gradients (SVG) in a flat plate boundary layer is investigated where disturbances of different types are introduced in the wall-bounded shear layer. The experimental investigations are aimed at; (i) generating stable and steady streamwise streaks in the boundary layer which set up spanwise gradients in the mean flow, and (ii) attenuating disturbance energy growth in the streaky boundary layers and hence delaying the onset of turbulence transition. LÄS MER

  3. 12. Rate Limiting Factors For Protein Folding

    Författare :Maria Berggård Silow; Biokemi och Strukturbiologi; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; kinetic competition; transient aggregation; diffusion control; reconfiguration time; collapse; osmolytes; broad barriers; Hammond behaviour; two-state; U1A; CI2; Proteins; enzymology; Proteiner; enzymologi;

    Sammanfattning : Abstract. This thesis describes factors that are rate limiting for the folding of two small proteins, U1A and CI2 which fold without accumulating intermediates. The [GdnHCl] dependencies of the unfolding- and refolding kinetics of U1A display downward curvatures. LÄS MER

  4. 13. Transition metal-catalyzed hydrogen transfer processes

    Författare :Oscar Verho; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES;

    Sammanfattning : The first part describes the synthesis of new analogues of Bäckvall’s catalyst with varying electronic properties and their application in the racemization of sec-alcohols. The racemization involves two key steps: (i) β-hydride elimination (dehydrogenation of the alcohol) and (ii) hydride re-addition to the intermediate ketone. LÄS MER

  5. 14. Modelling of Turbulent Flow and Heat Transfer for Building Ventilation

    Författare :Peng Shia-Hui; Chalmers tekniska högskola; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; NATURVETENSKAP; NATURAL SCIENCES; large eddy simulation; turbulent buoyant convection; ventilation performance assessment; purging flow rate; SGS modelling; ventilation flow; stochastic Markov chain model; turbulence modelling; LRN k-w model; two-equation models; building ventilation; transfer probability; transition regime; modified SGS buoyancy model; energy backscatter;

    Sammanfattning : This thesis contributes to studies on the assessment of building ventilation performance and the development of turbulence models accounting for Low-Reynolds-number (LRN) effects and buoyant convection with heat transfer. Assessments of building ventilation performance are discussed with respect to indoor air distribution and passive contaminant dispersion. LÄS MER

  7. 15. Transition Metal Mediated Transformations of Carboranes

    Författare :Ludvig Eriksson; Kalman Szabo; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Chemistry; carborane; isoquinoline; PK11195; peripheral bensodiazepine receptor; Cu I Iodide; iodinated carborane; palladium; isotopic exchange; Herrmann’s Catalyst; Heck reaction; Suzuki-Miyaura reaction; cross coupling; arylation; olefination; 125-iodine; radiolabelling; carboraneboronic ester; BNCT; 2-iodo-; Kemi; Chemistry; Kemi; organisk kemi; Organic Chemistry;

    Sammanfattning : This thesis describes the use of copper and palladium to mediate transformations of carboranes, especially p-carborane.1-(1-p-carboranyl)-N-methyl-N-(2-butyl)-3-isoquinolinecarboxamide, a carborane containing analogue of the peripheral benzodiazepine receptor (PBR) ligand PK11195, has been synthesised. LÄS MER