Sökning: "Transition Metal Complex"

Visar resultat 1 - 5 av 142 avhandlingar innehållade orden Transition Metal Complex.

  1. 1. Transition Metal Hydrides : Biomimetic Studies and Catalytic Applications

    Författare :Jesper Ekström; Hans Adolfsson; Jonathan Williams; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; transition metals; catalysis; bioinorganic chemistry; hydrides; Organic chemistry; Organisk kemi; Organic Chemistry; organisk kemi;

    Sammanfattning : In this thesis, studies of the nature of different transition metal-hydride complexes are described. The first part deals with the enantioswitchable behaviour of rhodium complexes derived from amino acids, applied in asymmetric transfer hydrogenation of ketones. LÄS MER

  3. 2. Modeling Photofunctional Transition Metal Complexes

    Författare :Iria Bolano Losada; NanoLund: Centre for Nanoscience; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; density functional theory; earth-abundant; molecular dynamics; quantum chemistry; photosensitizer; photophysics; photochemistry; solar fuels; solar energy conversion; transition metal complexes;

    Sammanfattning : Transition metal complexes play a crucial role in solar energy conversion. These coordination compounds have promising applications in dye-sensitized solar cells and photocatalysis, with particular interest in solar fuel production. LÄS MER

  4. 3. Carbenes: The Gathering : Photophysics of Transition Metal Carbene Complexes

    Författare :Nidhi Kaul; Leif Hammarström; James K. McCusker; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; photophysics; time-resolved spectroscopy; transition-metal complexes; Kemi med inriktning mot kemisk fysik; Chemistry with specialization in Chemical Physics;

    Sammanfattning : This thesis explores the photophysics of some transition-metal complexes (TMCs) which utilize N-heterocyclic carbenes as ligands. After a historical interlude which traces the development of the broader field of transition metal complexes and their photophysical investigations, there is an overview of theoretical concepts and the spectroscopic methods employed. LÄS MER

  5. 4. Transition Metal-Catalyzed Redox Reactions : A Journey from Homogeneous Ruthenium to Heterogeneous Palladium Catalysis

    Författare :Oscar Verho; Jan-Erling Bäckvall; Manfred Reetz; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; organisk kemi; Organic Chemistry;

    Sammanfattning : The first part of the thesis covers the development and utilization of electronically modified (pentaarylcyclopentadienyl)Ru-complexes in the racemization of secondary alcohols. This study revealed that the electronic properties of the substrate were the main factors dictating whether β-hydride elimination or hydride re-addition becomes the rate-determining step of the racemization process. LÄS MER

  7. 5. Microstructure aspects of transition metal carbide thin films

    Författare :Jun Lu; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Chemistry; vapour deposition; transition metal carbide; nanocrystallinity; epitaxy; Kemi; Chemistry; Kemi; Inorganic Chemistry; oorganisk kemi;

    Sammanfattning : Transition metal carbides are important refractory materials used in many thin film applications. In this thesis, several transition metal carbides have been deposited using different chemical vapour deposition (CVD) and evaporation processes. In particular, the phase composition and microstructure of these carbide films have been studied. LÄS MER