Sökning: "Thorium IV"
Visar resultat 1 - 5 av 8 avhandlingar innehållade orden Thorium IV.
1. Coordination Chemistry of Actinide and Lanthanide Ions
Sammanfattning : .... LÄS MER
2. Studies of actinides in a superanoxic fjord
Sammanfattning : Water column and sediment profiles of plutonium, americium, thorium and uranium have been obtained in the superanoxic Framvaren fjord, southern Norway. The concentrations of bomb test fallout Pu, Am as well as 'dissolved' Th in the bottom water are the highest recorded in the marine environment. LÄS MER
3. Surface Complexation Studies in An (Th, U(IV), Pu(VI)) Systems
Sammanfattning : Two-phase systems containing an electrolyte solution and a suspended solid were studied. The common denominator for the three systems examined in this work is that they contain actinides (elements of atomic numbers between 89 and 103) in either the solid phase or as a sorbate. Experiments were done on simple oxides. LÄS MER
4. Hydration, solvation and hydrolysis of multicharged metal ions
Sammanfattning : Structures of hydrated, solvated and hydrolyzed multicharged metal ions are determined by EXAFS and LAXS in solution, and by X-ray crystallography and EXAFS in the solid state. During hydrolysis, the nine-coordinate hydrated thorium(IV) ion is first transformed to a dimer, [Th₂(μ²-OH)₂(H₂O)₁₂]⁶⁺, then to a tetramer, [Th₄(μ²-OH)₈(H₂O)₁₆]⁸⁺, and finally to a hexamer, [Th₆(μ³-O₈)(H₂O)n]⁸⁺ with increasing pH and thorium(IV) concentration in an aqueous solution. LÄS MER
5. Advanced In-Core Fuel Cycles for the Gas Turbine-Modular Helium Reactor
Sammanfattning : In 1789 a German chemist, Martin Heinrich Klaproth, announced the discovery of a new element: uranium; few years later, the head of father of the modern chemistry, Antoine Lavoisier, was swept away by guillotine: a new era was destined to be opened, either where energy would have been produced in large scale by nuclear processes delivering hundreds of times the energy of chemical processes or where a mass of people, revolutionary or not, would have been melted down into a couple of seconds. After a quite long time, on the 2nd December 1942, the first nuclear reactor has been put into operation by Enrico Fermi in Chicago; few years later, came also the dark side utilization of fissile materials in Hiroshima and Nagasaki. LÄS MER
