Sökning: "Sustainable catalysis"

Visar resultat 6 - 10 av 53 avhandlingar innehållade orden Sustainable catalysis.

  1. 6. Palladium(II)-Catalysed Heck and Addition Reactions : Exploring Decarboxylative and Desulfitative Processes

    Författare :Bobo Skillinghaug; Mats Larhed; Antonio de la Hoz Ayuso; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Palladium; catalysis; palladium II catalysis; synthesis; Heck; carboxylic acid; sulfinic acid; sodium sulfinate; nitrile; styrene; ketone; aryl ketone; electrospray ionization mass spectrometry; density functional theory; microwave heating; continuous flow; Chemistry with specialization in Organic Chemistry; Kemi med inriktning mot organisk kemi;

    Sammanfattning : Palladium complexes have the ability to catalyse cross-coupling of two organic moieties through the formation of transient metal-carbon bonds, thus bringing them closer to each other to facilitate the formation of a new bond. Palladium-catalysed coupling reactions are one of the most important carbon-carbon forming reactions available to organic chemists and many of these reactions rely on the reactivity of aryl-palladium complexes. LÄS MER

  2. 7. N-Heterocyclic Carbene Catalysis in Organic Synthesis - A Green Chemistry Approach

    Författare :Linda Ta; Chalmers tekniska högskola; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; NATURVETENSKAP; NATURAL SCIENCES; aerobic oxidation; ionic liquid; sustainability; NHC catalysis; oxidative NHC catalysis; green chemistry; OTHO; Organocatalysis;

    Sammanfattning : The twelve principles of green chemistry were created as a response to the multiple environmental issues caused by the release of waste from the chemical industry. The principles acts as a guide in the development of sustainable chemical processes for the syntheses of important molecules needed to sustain our living standards. LÄS MER

  3. 8. Development of catalytic enantioselective C-C bond-forming and cascade transformations by merging homogeneous or heterogeneous transition metal catalysis with asymmetric aminocatalysis

    Författare :Samson Afewerki; Armando Córdova; MICHELANGELO GRUTTADAURIA; Mittuniversitetet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; asymmetric catalysis; transition metals; aldehydes; heterogeneous catalysis; amino acid; organocatalysis; α-allylation; β-alkylation; dynamic transformations; polysubstituted; carbocycles; spirocyclic oxindoles; all-carbon quaternary stereocenters;

    Sammanfattning : Chiral molecules play a central role in our daily life and in nature, for instance the different enantiomers or diastereomers of a chiral molecule may show completely different biological activity. For this reason, it is a vital goal for synthetic chemists to design selective and efficient methodologies that allow the synthesis of the desired enantiomer. LÄS MER

  4. 9. Iron or Copper? - Method Development and Mechanistic Studies on Cross-Coupling Reactions

    Författare :Per-Fredrik Larsson; Göteborgs universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Iron; Copper; Transition metal; Cross-coupling; Reaction mechanism; Kinetic investigation; Hammett study; Sustainable catalysis; Trace-metal; Mass-transfer; Ligand development; Ligand scope;

    Sammanfattning : The area of catalysis has had an immeasurable impact on modern society. This has been acknowledged through several Nobel prizes during the 20th century ranging from Haber (1918) for the synthesis of ammonia to Richard F. Heck, Ei-ichi Negishi, and Akira Suzuki (2010) for palladium-catalyzed cross-coupling reactions. LÄS MER

  5. 10. Water splitting by heterogeneous catalysis

    Författare :Henrik Svengren; Mats Johnsson; Tomas Edvinsson; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Faradaic efficiency; electrocatalysis; electrolysis; water oxidation; hydrogen reduction; H2; O2; mass spectrometry; Inorganic Chemistry; oorganisk kemi;

    Sammanfattning : A sustainable solution for meeting the energy demands at our planet is by utilizing wind-, solar-, wave-, thermal-, biomass- and hydroelectric power. These renewable and CO2 emission-free energy sources are highly variable in terms of spatial and temporal availability over the Earth, introducing the need for an appropriate method of storing and carrying energy. LÄS MER