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Visar resultat 1 - 5 av 66 avhandlingar som matchar ovanstående sökkriterier.

  1. 1. The Fate of Sulfur during Oxy-Fuel Combustion

    Författare :Daniel Fleig; Chalmers tekniska högskola; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; pulverized coal combustion; oxy-coal; SO3; Oxy-fuel; SO2; sulfur;

    Sammanfattning : Oxy-fuel combustion, where air is replaced by O2 and recycled flue-gas to enrich combustion products, is one of the main CO2 capture technologies suitable for large-scale coal-fired power plants. The changed combustion conditions in oxy-fuel combustion influences the sulfur chemistry, which has recently been the subject of increased attention due to the importance of sulfur species in corrosion and flue-gas cleaning issues. LÄS MER

  2. 2. Structure and bonding of sulfur-containing molecules and complexes

    Författare :Emiliana Damian Risberg; Magnus Sandström; Ingmar Persson; Tsun-Kong Sham; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Sulfur species; x-ray absorption and vibrational spectroscopy; TP-DFT calculations; Chemistry; Kemi; strukturkemi; Structural Chemistry;

    Sammanfattning : Synchrotron-based spectroscopic techniques enable investigations of the many important biological and environmental functions of the ubiquitous element sulfur. In this thesis the methods for interpreting sulfur K-edge X-ray absorption near edge structure (XANES) spectra are developed and applied for analyses of functional sulfur groups. LÄS MER

  3. 3. Chemical Speciation of Sulfur and Metals in Biogas Reactors : Implications for Cobalt and Nickel Bio-uptake Processes

    Författare :Sepehr Shakeri Yekta; Bo Svensson; Ulf Skyllberg; Åsa Danielsson; Charles Banks; Linköpings universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Biogas; Anaerobic digestion; Chemical speciation; bio-uptake; Sulfur; Iron; Cobalt; Nickel; Biogas; Anaerob nedbrytning; Kemisk speciering; Bio-upptag; Svavel; Järn; Kobolt; Nickel;

    Sammanfattning : A balanced supply of micronutrients, including metals such as iron (Fe), cobalt (Co), and nickel (Ni), is required for the efficient and stable production of biogas. During biogas formation, the uptake of micronutrient metals by microorganisms is controlled by a complex network of biological and chemical reactions, in which reduced sulfur (S) compounds play a central role. LÄS MER

  4. 4. Sulfur-Related Conservation Concerns in Marine Archaeological Wood : The Origin, Speciation and Distribution of Accumulated Sulfur with Some Remedies for the Vasa

    Författare :Yvonne Fors; Magnus Sandström; Ian MacLeod; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Sulfur accumulation; marine archaeological wood; Vasa; acidity; iron; ammonia; x-ray spectroscopy; cellulose; Chemistry; Kemi; strukturkemi; Structural Chemistry;

    Sammanfattning : Synchrotron-based sulfur spectroscopy reveals a common concern for marine archaeological wood from seawater: accumulation of reduced sulfur compounds in two pathways. The distribution of sulfur species in the oak wood cell structure was mapped by scanning x-ray spectro-microscopy (SXM). LÄS MER

  5. 5. RhPt and Ni based catalysts for fuel reforming in energy conversion

    Författare :Angélica Viviana González Arcos; Lars J. Pettersson; Klas Engvall; Anker Jensen; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; RhPt bimetallic catalysts; Ni catalysts; ceria-zirconia; potassium tungsten bronze; zirconium dioxide; autothermal reforming; biodiesel; diesel; sulfur; deactivation; tar reforming; steam reforming; biomass gasification; auxiliary power units; naphthalene; Chemical Engineering; Kemiteknik;

    Sammanfattning : Although current trends in global warming are of great concern, energy demand is still increasing, resulting in increasing pollutant emissions. To address this issue, we need reliable renewable energy sources, lowered pollutant emissions, and efficient and profitable processes for energy conversion. LÄS MER