Sökning: "Solvent-free reactions"

Visar resultat 1 - 5 av 8 avhandlingar innehållade orden Solvent-free reactions.

  1. 1. Synthesis of Non-Natural Aromatic Amino Acids Derivatives Solvent-free reactions-Versatile building blocks-Galectin inhibitors

    Författare :Erik Tullberg; Centrum för analys och syntes; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Organisk kemi; Organic chemistry; Naturvetenskap; Natural science; Multivalent galectin inhibitors; Multifunctional molecules; Amino Acids; Solvent-free reactions;

    Sammanfattning : This thesis deals with three topics concerning the synthesis of non-natural also known as unnatural amino acid derivatives. In the first, solvent-free reaction conditions for the Heck reaction were developed that were superior to previous conditions because the reaction time could be reduced and the work-up procedure simplified. LÄS MER

  3. 2. Multicomponent Catalytic Reactions : Theoretical and Experimental Studies

    Författare :Martin Pauze; Enrique Gomez Bengoa; Belen Martin-Matute; Vincent Gandon; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; C-H Activation; Quaternary Quinolinium; Organocatalyst; Transition Metal Catalyst; Umpolung Strategy; Multi-step Reactions; Mechanistic Investigation; Density Functional Theory; organisk kemi; Organic Chemistry;

    Sammanfattning : In this thesis, Density Functional Theory (DFT) methods have been applied to study the mechanisms of three different multicomponent organic reactions. Also, a new synthetic procedure for the preparation of quinolinium salts is presented, and its mechanism also studied by DFT calculations. LÄS MER

  4. 3. Chemo-Enzymatic Epoxidation of Unsaturated Fatty Acids

    Författare :Cecilia Orellana Coca Åkerman; Bioteknik; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Bioteknik; Biotechnology; solvent-free process.; Candida antarctica lipase B esterification; chemo-enzymatic epoxidation; Unsaturated fatty acids; epoxides;

    Sammanfattning : Epoxy fatty acids are useful molecules and find a number of applications e.g. as PVC plasticisers and stabilisers, additives in polyurethane production, reactive diluents in paints, corrosion protection agents, etc. LÄS MER

  5. 4. LIPASES AND PHOSPHOLIPASES IN PHOSPHOLIPID SYNTHESIS

    Författare :Carmen Virto; Bioteknik; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; transphosphatidylation; acylation; vinyl ester; Phospholipid synthesis; lysophospholipid; kinetics; Biotechnology; Bioteknik;

    Sammanfattning : The synthesis of phospholipids with defined fatty acid and polar head composition catalysed by lipases and phospholipases was investigated. Lipases from Rhizopus arrhizus and Candida antarctica were used for the direct acylation of DL-a-glycerophosphate and L-a-glycerophosphatidylcholine, with different fatty acids. LÄS MER

  7. 5. Lipase-Mediated Syntheses of Trimethylolpropane-Based Biolubricant and Cyclic Carbonate

    Författare :Amin Bornadel; Bioteknik; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY;

    Sammanfattning : Abstract Biocatalysis is considered as benign and efficient alternative to chemical catalysis for organic syntheses. Lipases are the most versatile biological catalysts implemented so far with great potential for production of different chemicals and materials in non-conventional reaction media. LÄS MER