Sökning: "Sn Oct 2"

Visar resultat 1 - 5 av 6 avhandlingar innehållade orden Sn Oct 2.

1. 1. Novel methods to synthesize aliphatic polyesters of vivid architectures

   Författare :Rajiv Srivastava; Ann-Christine Albertsson; Ronnie Palmgren; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Polyesters; 1; 5-dioxepan-2-one; Caprolactone; Sn Oct 2; Enzyme; Lipase-CA; Ring-Opening Polymerization; Architecture; Tissue Engineering; Polymer chemistry; Polymerkemi;

   Sammanfattning : Cross-linked films of ε-caprolactone (CL) and 1,5-dioxepan-2-one (DXO) having various mole fractions of monomers and different cross-link densities were prepared using 2,2’-bis-(-caprolactone-4-yl) propane (BCP) as cross-linking agent and Sn(Oct)2 as catalyst. Reaction parameters were examined to optimize the film-forming conditions. LÄS MER

3. 2. Aliphatic Polyesters for Soft Tissue Engineering : Development from Conventional Organometallic to Novel Enzymatic Catalysis

   Författare :Rajiv Kumar Srivastava; Ann-Christine Albertsson; Stanishaw Penzzek; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; aliphatic polyester; 1; 5-dioxepan-2-one; ε-caprolactone; L-lactide; D-lactide; D; L-lactide; enzyme; lipase CA; lipase PS; Polymer chemistry; Polymerkemi;

   Sammanfattning : The development of macromolecules with defined structure and properties, aimed specifically for biomedical applications, has resulted in diverse biodegradable polymers with advanced architectures. Among them, aliphatic polyesters synthesized by ring-opening polymerization (ROP) of lactones and lactides have a leading position due to their good mechanical properties, hydrolyzability and biocompatibility. LÄS MER

4. 3. Macromolecular design and architecture of aliphatic polyesters

   Författare :Karin Odelius; Ann-Christine Albertsson; Helmut Keul; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Ring-opening polymerization; L-lactide; 1; 5-dioxepane-2-one; ε-caprolactone; Polymerization kinetics; Star-shaped architecture; Spirocyclic tin initiator; Polymer chemistry; Polymerkemi;

   Sammanfattning : Public health care has reached a level where tissue or organ reconstruction by means of biodegradable short-term implants via e.g. tissue engineering will be practicable in the near future. LÄS MER

5. 4. Macromolecular synthesis of functional degradable aliphatic polyesters and porous scaffold design

   Författare :Sofia Målberg; Ann-Christine Albertsson; Anders Södergård; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; functional polyesters; condensation polymerization; L-lactide; ε-caprolactone; triblock copolymer; mechanical properties; porous scaffolds; tissue engineering; ring-opening polymerization; Bi III acetate; creatinine; stannous 2-ethylhexanoate; enzyme; degradation products; Polymer chemistry; Polymerkemi;

   Sammanfattning : There is an increasing demand for new materials in biomedical applications with material properties that are highly specific for each application area. The search for new materials requires the creation of materials with suitable mechanical properties, functionalities, three-dimensional structures and a controlled degradation profile. LÄS MER

7. 5. Synthesis of Biomedical Polymers and Scaffold Design

   Författare :Therese Tyson; Ann-Christine Albertsson; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; ring-opening polymerization; tin alkoxide initiator; stannous octoate; poly p-dioxanone ; copolymer; L-lactide; trimethylene carbonate; degradable porous scaffold; Polymer chemistry; Polymerkemi;

   Sammanfattning : This work has focused on the development of new improved synthesis methods of biodegradable aliphatic polymers and on the preparation of porous scaffolds for tissue engineering applications. The aim of the first part of the work was the synthesis of poly(p-dioxanone) (PPDX) homopolymers with high molecular weights using the cyclic tin alkoxide initiator 1-di-n-butyl-1-stanna-2,5-dioxacyclopentane. LÄS MER