Sökning: "Ru-complexes"
Visar resultat 1 - 5 av 6 avhandlingar innehållade ordet Ru-complexes.
1. Atomic Scale Modelling in Photoelectrocatalysis : Towards the Development of Efficient Materials for Solar Fuel Production
Sammanfattning : Using sunlight to produce valuable chemicals has been pointed out as an interesting alternative to deal with the well-known environmental problem related to the use of fossil fuels for energy generation. Thus, it is crucial for this field the development of novel photocatalysts that could drive the uphill reactions with high efficiency while presenting low price and toxicity. LÄS MER
2. Artificial Water Splitting: Ruthenium Complexes for Water Oxidation
Sammanfattning : This thesis concerns the development and study of Ru-based water oxidation catalysts (WOCs) which are the essential components for solar energy conversion to fuels. The first chapter gives a general introduction about the field of homogenous water oxidation catalysis, including the catalytic mechanisms and the catalytic activities of some selected WOCs as well as the concerns of catalyst design. LÄS MER
3. Studies of Semiconductors Modified with Nanoscale Light Absorbers for Solar Cell Application
Sammanfattning : Recently, materials such as hole conductors (CuI, CuSCN) and light absorbers (Ru-complexes, CuInS2) have been actively investigated for application in nanocrystalline solar cells. In this thesis combinations of these materials have been studied. LÄS MER
4. Transition Metal-Catalyzed Redox Reactions : A Journey from Homogeneous Ruthenium to Heterogeneous Palladium Catalysis
Sammanfattning : The first part of the thesis covers the development and utilization of electronically modified (pentaarylcyclopentadienyl)Ru-complexes in the racemization of secondary alcohols. This study revealed that the electronic properties of the substrate were the main factors dictating whether β-hydride elimination or hydride re-addition becomes the rate-determining step of the racemization process. LÄS MER
5. Life of Excitons in Artificial Photosynthetic Antennas
Sammanfattning : Due to the predicted energy crisis when fossil fuels will be exhausted it is important to search for alternative energy sources. Utilizing sunlight via artificial photosynthesis is an interesting possibility. LÄS MER