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1. 1. Palladium-Catalyzed Synthesis and Transformations of Organometallic Compounds

   Författare :Olov Wallner; Kálmán Szabó; Robin Bedford; Stockholms universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; palladium; Organic chemistry; Organisk kemi;

   Sammanfattning : This thesis is focused on two important fields of palladium catalysis: the development of electrophilic allylic substitution reactions via bis-allylpalladium intermediates; and application of palladium pincer-complexes in the synthesis and transformations of organometallic compounds.Palladium-catalyzed electrophilic allylation of aldehyde and imine substrates could be achieved using readily available allyl chlorides and acetates by employing hexamethylditin or bis(pinacolato)diboron reagents. LÄS MER