Sökning: "Polyelectrolyte adsorption"

Visar resultat 1 - 5 av 58 avhandlingar innehållade orden Polyelectrolyte adsorption.

  1. 1. Polyelectrolyte adsorption on oppositely charged surfaces - Conformation and adsorption kinetics

    Författare :Lars-Erik Enarsson; Lars Wågberg; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Polyelectrolyte adsorption; adsorption kinetics; adsorption isotherms; conformation; bridging; stagnation point adsorption reflectometry; quartz crystal microgravimetry; polyelectrolyte titration; cationic polyacrylamide; cationic dextran; colloidal silica; silica surfaces; pulp; Chemistry; Kemi;

    Sammanfattning : Denna avhandling presenterar experimentella studier av polyelektrolytadsorption på motsatt laddade ytor, där substrat av både kiseloxid och blekt barrsulfatmassa har använts. Ett huvudsakligt syfte med denna forskning var att karaktärisera konformationen hos adsorberade skikt av katjonisk polyakrylamid (CPAM) i jämförelse med katjonisk dextran (Cdextran) och relatera denna information till inbindningskapaciteten av kolloidal kiselsyra. LÄS MER

  3. 2. The effects of cellulosic fiber charges on polyelectrolyte adsorption and fiber-fiber interactions

    Författare :A. Elisabet Horvath; Lars Wågberg; Stefan Zauscher; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; adsorption; electrolyte; polyelectrolyte; polyelectrolyte titration; stoichiometry; fluorescence; CLSM; carboxymethylation; ESCA; charge ration; colloidal interactions; mechanical forces; network strength; floc; CPM; rehometer; Cellulose and paper engineering; Cellulosa- och pappersteknik;

    Sammanfattning : The surface charges of cellulosic fibers contribute to several papermaking operations that influence the manufacture and final properties of paper. This thesis investigates the effect of the surface charges on wet-end chemistry, e.g. LÄS MER

  4. 3. On the interactions in cellulose systems : surface forces and adsorption

    Författare :Monika Österberg; KTH; []
    Nyckelord :cellulose; hemicellulose; xylan; lignin; surface forces; adsorption; polyelectrolyte; SFA; AFM; ESCA; Langmuir-Blodgett films; chitosan; steric forces; bridging; adhesion;

    Sammanfattning : In this thesis the interactions in cellulose systems havebeen studied with emphasis on surface forces and adsorptionphenomenon. The study was limited to surfaces and polymers ofinterest for papermaking. LÄS MER

  5. 4. Polyelectrolyte complexes : their preparation, adsorption behaviour and effect on paper properties

    Författare :Caroline Ankerfors; Lars Wågberg; Monica Ek; Tom Lindström; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Cellulose and paper engineering; Cellulosa- och pappersteknik;

    Sammanfattning : In this work, the formation of polyelectrolyte complexes (PECs) has been studied using a jet mixing method not previously used for mixing polyelectrolytes. The PECs were formed from two weak polyelectrolytes, i.e. LÄS MER

  7. 5. Polyelectrolytes : Bottle-Brush Architectures and Association with Surfactants

    Författare :Ali Naderi; Per M. Claesson; Orlando Rojas; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Polyelectrolyte; Surfactant; Bottle-Brush Polyelectrolyte; Comb Polyelectrolyte; Non-Equilibrium State; Polymer Architecture; Adsorption; Desorption; Association; Excluded Volume; Light Scattering; SFA; AFM; QCM-D; Turbidimeter; Mica; Silica; Surface Forces; Surface and colloid chemistry; Yt- och kolloidkemi;

    Sammanfattning : This thesis has the dual purpose of raising awareness of the importance of the mixing protocol on the end products of polyelectrolyte-oppositely charged surfactant systems, and to contribute to a better understanding of the properties of bottle-brush polyelectrolytes when adsorbed onto interfaces. In the first part of this thesis work, the effects of the mixing protocol and the mixing procedure on formed polyelectrolyte-oppositely charged surfactant aggregates were investigated. LÄS MER