Sökning: "Pd Al2O3"

Visar resultat 6 - 10 av 29 avhandlingar innehållade orden Pd Al2O3.

  1. 6. Studies of NOx Storage Catalysts - Preparation, Characterization, Sulfur Deactivation and Micro Kinetic Modelling

    Författare :JAZAER DAWODY; Chalmers tekniska högskola; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; kinetic modelling; metal oxide additives; NO oxidation; Zeta potential; FTIR; SO2 oxidation; Al2O3; NOx storage and reduction catalysts; TEM; BaCO3; SEM; Pt precursors; sulfur deactivation;

    Sammanfattning : For the protection of the global environment, it is essential to decrease the emissions of CO2 which is a green house gas. Lean-burn and diesel engines offer relatively low CO2 emissions and good fuel economy. LÄS MER

  2. 7. Multiscale modelling of total pressure effects on complete methane oxidation over Pd/Al2O3

    Författare :Carl-Robert Florén; Chalmers tekniska högskola; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; palladium oxide; mass and heat transport; multiscale modelling; reactor modelling; methane oxidation; first-principles calculations;

    Sammanfattning : The models used in heterogeneous catalysis are becoming more advanced and the literature shows an increased interest in incorporating the atomistic scale into microkinetics. Coupling kinetics based on first-principles calculations to macroscopic effects can pave the way towards more comprehensive modelling methods and to tailored catalyst designs. LÄS MER

  3. 8. Effects of trace elements in biodiesel on the performance of diesel oxidation catalysts in heavy-duty vehicles

    Författare :Jonas Granestrand; Lars Pettersson; Todd J. Toops; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Diesel Oxidation catalyst; heavy-duty vehicles; catalyst deactivation; biodiesel; NAP-XPS; XANES; Phosphorus; alkali metals; Pt Pd Al2O3; Chemical Engineering; Kemiteknik;

    Sammanfattning : To reduce net greenhouse gas emissions, a shift towards adoption of biofuels is ongoing in the transport sector. Heavy-duty diesel vehicles are equipped with aftertreatment equipment, comprising of catalysts and filters, and how this equipment is affected by the use of biofuels is not yet fully understood. LÄS MER

  4. 9. Spectroscopic investigation of palladium catalysts during wet methane oxidation

    Författare :Peter Velin; Chalmers tekniska högskola; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; Methane oxidation; Water inhibition; XAS; DRIFTS; Supported palladium; Environmental catalysis; Operando spectroscopy; Sustainable transports;

    Sammanfattning : Abatement of the strong greenhouse gas methane in vehicle applications by use of catalytic end-of-pipe technologies is challenging due to the prevailing reaction conditions with low temperatures and high water content. In this thesis, the mechanisms behind low-temperature water inhibition of lean methane oxidation over palladium-based catalysts have been studied using an integrated experimental approach including wet-chemical preparation of model catalysts with systematic variation of key performance parameters, transient measurements of reaction kinetics in chemical flow reactor, and operando infrared and X-ray absorption spectroscopic characterisation. LÄS MER

  5. 10. New Materials in Environmental Catalysis

    Författare :Magnus Skoglundh; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; Cobalt; Copper; Xylene oxidation; Platinum; Carbon monoxide oxidation; exhaust gas catalysis; Rhodium; Palladium; Nitric oxide reduction; perovskites;

    Sammanfattning : This thesis presents new approaches to the control of emissions within the field of environmental catalysis. Three catalytic systems; bimetallic catalysts, perovskites and promoted catalysts have been prepared and evaluated for complete oxidation of volatile organic compounds and for simultaneous conversion of CO, hydrocarbons and nitrogen oxides. LÄS MER