Sökning: "Paramagnetic state"

Visar resultat 1 - 5 av 65 avhandlingar innehållade orden Paramagnetic state.

  1. 1. Probing Paramagnetic Systems by Solid-State NMR Spectroscopy

    Författare :José P. Carvalho; Andrew J. Pell; Sharon Ashbrook; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Solid-state NMR; Magic-Angle Spinning; Paramagnetic NMR; Frequency-Swept Adiabatic Pulses; Quantum Chemistry; Quadrupolar Interaction; Physical Chemistry; fysikalisk kemi;

    Sammanfattning : Paramagnetic systems have a wide range of applications ranging from energy storage or conversion to catalytic processes, metalloproteins and light-emitting materials. Over the recent years nuclear magnetic resonance (NMR) spectroscopy has become an established tool for studying the structural and electronic properties of these systems, largely because it can provide a link between the structure and the bulk properties. LÄS MER

  3. 2. The paramagnetic Meissner effect

    Författare :Evie Papadopoulou; Uppsala universitet; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Materials science; high-temperature superconductivity; Bi-based compounds; paramagnetic Meissner effect; ageing; disordered magnets; chiral-glass; Materialvetenskap; Materials science; Teknisk materialvetenskap; Solid State Physics; fasta tillståndets fysik;

    Sammanfattning : The low field dynamics of some high temperature superconductors have been studied experimentally, using SQUID magnetometry. The research has been focused on the so called Paramagnetic Meissner Effect (PME), a phenomenon seen in some high temperature superconducting cuprates. LÄS MER

  4. 3. Paramagnetic states of diiron carboxylate proteins

    Författare :Nina Voevodskaya; Astrid Gräslund; Peter Brzezinski; Howard Dalton; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; electron paramagnetic resonance; diiron carboxilate proteins; ribonucleotide reductase; alternative oxidase; Biophysics; Biofysik;

    Sammanfattning : Diiron carboxylate proteins constitute an important class of metall-containing enzymes. These proteins perform a multitude of reactions in biological systems that normally involve activation of molecular oxygen at the diiron site. LÄS MER

  5. 4. New solid-state NMR methods for exciting and separating anisotropic interactions of spin I=1 nuclei

    Författare :Rihards Aleksis; Andrew Pell; Robert Schurko; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; solid-state NMR; quadrupolar; paramagnetic shifts; spinning solids; materials; Physical Chemistry; fysikalisk kemi;

    Sammanfattning : Solid-state NMR has become an essential tool for structural characterisation of materials, in particular systems with poor crystallinity and structural disorder. In recent years, a surge of interest has been observed for the study of paramagnetic systems, in which the interaction between nuclei and unpaired electrons allows to probe the electronic structure and properties of materials more directly. LÄS MER

  7. 5. Photosynthetic Oxygen Evolution - EPR studies of the manganese cluster of photosystem II

    Författare :Sindra Peterson Årsköld; Biokemi och Strukturbiologi; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; S2 state; second cycle; Biochemistry; Metabolism; Biokemi; metabolism; S0 state; light-adaptation; pulsed EPR; methanol; relaxation; microwave power saturation; S-cycle; Oxygen-evolving complex; Water-oxidizing complex;

    Sammanfattning : In this thesis, a new electron paramagnetic resonance (EPR) signal from photosystem II is presented. The signal is shown to originate from the S0 oxidation state of the oxygen-evolving complex (OEC). LÄS MER