Sökning: "Palladium"

Visar resultat 11 - 15 av 320 avhandlingar innehållade ordet Palladium.

  1. 11. Structural Properties of Palladium-Manganese Alloys

    Författare :Alexander J Jaworowski; Lunds universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; transition metal; structure; growth; adsorption; core level photoemission. scanning tunneling microscopy; fourier-transform infrared spectroscopy; Manganese; Palladium; Rhodium; Molybdenum; NO; CO; alloy; O; Physics; Fysik; Semiconductory physics; Halvledarfysik; Fysicumarkivet A:2001:Jaworowski;

    Sammanfattning : Structural properties of adsorbed overlayers on well-defined single crystals and of Palladium-Manganese surface alloys formed on Pd(100) have been investigated using synchrotron-based photoemission, scanning tunneling microscopy and Fourier-transform infrared spectroscopy. The experimental valence electronic structure of PdMn systems on Pd(100) is compared to density functional calculations (DFT). LÄS MER

  3. 12. Exploring Palladium-Mediated 11C/12C-Carbonylation Reactions : PET Tracer Development Targeting the Vesicular Acetylcholine Transporter

    Författare :Sara Roslin; Mats Larhed; Gunnar Antoni; Jonas Eriksson; Luke Odell; Victor Pike; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; Carbonylation; palladium; carbon-11; radiochemistry; positron emission tomography; vesicular acetylcholine transporter; vesamicol; alkyl halide; oxidative carbonylation; acylamidine; oxadiazole; heterocycle; Farmaceutisk vetenskap; Pharmaceutical Science;

    Sammanfattning : The work presented herein describes the utilization and exploration of palladium-mediated incorporations of carbon monoxide and/or [11C]carbon monoxide into compounds and structural motifs with biological relevance.The first part of the thesis describes the design, synthesis and 11C-labeling of prospective PET tracers for the vesicular acetylcholine transporter (VAChT), a target affected in several neurodegenerative diseases. LÄS MER

  4. 13. Coke on Supported Palladium and Platinum Catalysts

    Författare :Mikael Larsson; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; TPO; palladium; deactivation; coke; propane dehydrogenation; microbalance; vegetable oil hydrogenation; acetylene hydrogenation; catalysis; platinum;

    Sammanfattning : Catalyst deactivation by coke formation has been investigated in three heterogeneous catalytic processes, propane dehydrogenation, acetylene hydrogenation and hydrogenation of vegetable oil. Palladium and/or platinum supported on alumina were used as catalysts in all reactions. LÄS MER

  5. 14. Selectivity in Palladium- and Enzyme-Catalyzed Reactions : Focusing on Enhancement of Reactivity

    Författare :Peter Nilsson; Anders Hallberg; Mats Larhed; Matthias Beller; Uppsala universitet; []
    Nyckelord :MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; Pharmaceutical chemistry; Palladium; Heck; PCR; Microwaves; Farmaceutisk kemi; Pharmaceutical chemistry; Farmaceutisk kemi;

    Sammanfattning : Catalysis has a profound impact on all living species on the earth. Nature’s catalysts, the enzymes, have the ability to selectively promote a specific bio-chemical transformation, given the required substrate. LÄS MER

  7. 15. Palladium-Catalyzed Synthesis and Transformations of Organometallic Compounds

    Författare :Olov Wallner; Kálmán Szabó; Robin Bedford; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; palladium; Organic chemistry; Organisk kemi;

    Sammanfattning : This thesis is focused on two important fields of palladium catalysis: the development of electrophilic allylic substitution reactions via bis-allylpalladium intermediates; and application of palladium pincer-complexes in the synthesis and transformations of organometallic compounds.Palladium-catalyzed electrophilic allylation of aldehyde and imine substrates could be achieved using readily available allyl chlorides and acetates by employing hexamethylditin or bis(pinacolato)diboron reagents. LÄS MER