Sökning: "Organic chemistry Organisk kemi indoles carbenium ions hexafluoroisopropanol hydride abstraction molybdenum cationic diene complexes"

Hittade 1 avhandling innehållade orden Organic chemistry Organisk kemi indoles carbenium ions hexafluoroisopropanol hydride abstraction molybdenum cationic diene complexes.

  1. 1. Organomolybdenum Complexes in Organic Synthesis- New methods for the Preparation of Cationic Diene Complexes and Applications to Synthesis

    Författare :Emelie Bjurling; Centrum för analys och syntes; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Organisk kemi; Organic chemistry; indoles; carbenium ions; hexafluoroisopropanol; hydride abstraction; molybdenum; cationic diene complexes;

    Sammanfattning : Indolyl substituted pyranyl- and cyclohexenyl molybdenum complexes were synthesised through stereoselective nucleophilic addition of indoles to the corresponding cationic 2H-pyran or cyclohexadiene molybdenum complex. Decomplexation of an allylic molybdneum complex by treatment with iodine gave 1-(4-iodo-2-cyclohexenyl)-1H-indole-3-carbonitrile in high regio-selectivity. LÄS MER