Sökning: "NATURVETENSKAP Kemi Fysikalisk kemi Yt- och kolloidkemi"

Visar resultat 11 - 15 av 31 avhandlingar innehållade orden NATURVETENSKAP Kemi Fysikalisk kemi Yt- och kolloidkemi.

1. 11. Mesoporous Silica Formed with Triblock Copolymers

   Författare :Katarina Flodström; Fysikalisk kemi; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Fysikalisk kemi; 1H NMR; TEM; SAXS; in situ; mechanism of formation; cubic Ia3d; cubic Im3m; Mesoporous; synthesis; Pluronic; SBA-16; SBA-15; hexagonal p6mm; synchrotron SAXS; Physical chemistry; amphiphilic polymers; silica;

   Sammanfattning : The formation of highly ordered mesoporous silica materials, using PEO-PPO-PEO amphiphilic triblock copolymers (so-called Pluronics) as structure directing agents, has been studied. The materials are formed through the addition of a silica source to a polymer solution of low concentration (2.5 wt ) under acidic conditions. LÄS MER

3. 12. Biomimetic Membranes: : Molecular Structure and Stability Studies by Vibrational Sum Frequency Spectroscopy

   Författare :Jonathan F.D. Liljeblad; Mark W. Rutland; Magnus C. Johnson; Tore Brinck; Lars Kloo; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Vibrational Sum Frequency Spectroscopy VSFS ; Langmuir monolayer; LB depositon; phospholipids; oxidation; biomimetic membranes; Surface and colloid chemistry; Yt- och kolloidkemi;

   Sammanfattning : In the research presented in this licentiate thesis the surface specific technique Vibrational Sum Frequency Spectroscopy, VSFS, combined with the Langmuir trough has been utilized to investigate Langmuir monolayers and Langmuir-Blodgett (LB) deposited mono- and bilayers of phospholipids. Their molecular structure, stability, and hydration were probed to gain additional understanding of important properties aiming at facilitating the use of such layers as model systems for biological membranes. LÄS MER

4. 13. Adsorption of biopolymers and their layer-by-layer assemblies on hydrophilic surfaces

   Författare :Maria Lundin; Eva Blomberg; Thomas Arnebrant; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Layer-by-layer; multilayer; adsorption; biopolymers; Chitosan; Heparin; Mucin; Albumin; Lysozyme; β-casein; SDS; QCM-D; Ellipsometri; DPI; TIRF; FRET; SFA; layer structure; solvent content; vertical diffusion; exponential growth; solid-liquid interface; deposition conditions; Surface and colloid chemistry; Yt- och kolloidkemi;

   Sammanfattning : It is widely known that surfaces play an important role in numerous biological processes and technological applications. Thus, being able to modify surface properties provides an opportunity to control many phenomena occurring at interfaces. LÄS MER

5. 14. Interfacial Properties of Biomacromolecular Model Systems: Surface Forces and Nanotribology

   Författare :Niklas Nordgren; Mark Rutland; Harry Brumer III; Robert Pelton; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; afm; surface force; friction; composite material; model surface; quartz crystal microbalance; dissipation; cellulose; xyloglucan; chitosan; colloidal probe; nanotribology; biomimetic; enzymatic; polysaccharide; graft; fiber; thiol; spring constant; calibration; lubrication; polyion; responsive.; Surface and colloid chemistry; Yt- och kolloidkemi;

   Sammanfattning : The nanotribology, adhesion and related interfacial properties of biomacromolecular systems have been studied.  The aim was to elucidate the role of physisorbed and chemically grafted bio-polymers implicated as mediators for cellulose based processing and material design. LÄS MER

7. 15. Polyelectrolyte complexes of bottle brush copolymers : Solution and adsorption properties

   Författare :Shovsky Alexander; Per M. Claesson; Tommy Nylander; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Surface and colloid chemistry; Yt- och kolloidkemi;

   Sammanfattning : The aim of this thesis work was to systematically investigate the physico-chemical properties of polyelectrolyte complexes (PECs) formed by bottle brush and linear polyelectrolytes in solution and at solid / liquid interfaces. Electrostatic self-assembly of oppositely charged macromolecules in aqueous solution is a versatile strategy to construction of functional nanostructures with easily controlled properties. LÄS MER