Sökning: "Molecular field splitting"

Visar resultat 16 - 19 av 19 avhandlingar innehållade orden Molecular field splitting.

  1. 16. Structural, Electronic and Reactive Properties of Pentapyridyl - Base Metal Complexes : Relevance for Water Oxidation Catalysis

    Författare :Manuel Boniolo; Johannes Messinger; Antoni Llobet; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Water oxidation; Base metal complexes; Redox potential; Spin crossover; Magnetic anisotropy; Chemistry with specialization in Molecular Biomimetics; Kemi med inriktning mot molekylär biomimetik;

    Sammanfattning : The rationalization of chemical-physical proprieties of transition metal complexes is fundamental in order to understand and tune their reactivity. In this thesis, a systematic investigation of the geometrical and electronic properties of [M(Py5OH)Cl]+ complexes (M= Mn, Fe, Co, Ni) has been performed, and their ability to act as molecular water oxidation catalysts has been probed. LÄS MER

  2. 17. Magnetic fields around massive protostars as traced by masers and dust emission

    Författare :Daria Dall` Olio; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; magnetic field – stars: formation – stars: massive – masers – dust – polarization – stars: individual: IRAS 18089-1732 – G9.62 0.19;

    Sammanfattning : It is not fully clear how the magnetic field acts during the first stages of star formation. A possible way to clarify its role is to observe the polarized light coming from masers and thermal dust emission. LÄS MER

  3. 18. ZnO Quantum Dots : Size Dependent Optical, Vibrational and Photoelectrochemical Properties

    Författare :Jesper Jacobsson; Tomas Edvinsson; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; ZnO; nanoparticels; quantum dots; Chemistry with specialization in Inorganic Chemistry; Kemi med inriktning mot oorganisk kemi;

    Sammanfattning : This thesis is devoted to quantum dots of ZnO in the size regime 2.5-10 nm.The focus is directed towards their size dependent properties with specialemphasis on the optical, vibrational and photocatalytic properties. The particleswere synthesized by hydrolysis in alkaline zinc acetate solution. LÄS MER

  4. 19. Polarization-resolved photoluminescence spectroscopy of III-nitride quantum dots

    Författare :Supaluck Amloy; Fredrik Karlsson; Per-Olof Holtz; Jørn M. Hvam; Linköpings universitet; []
    Nyckelord :;

    Sammanfattning : In this thesis, results from studies on (In)GaN quantum dots (QDs) are presented, including investigations of the structural, optical and electronic properties. The experimental studies were performed on GaN and InGaN QDs grown by molecular beam epitaxy, taking advantage of the Stranki-Krastanov growth mode for the GaN QD samples and the composition segregation for the InGaN QD samples. LÄS MER